Last updated: 2020-07-19

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Knit directory: Cant_eMLR/

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library(tidyverse)
library(lubridate)
library(patchwork)

1 Open clean data set

GLODAP <- read_csv(here::here("data/GLODAPv2_2020/_summarized_data_files",
                              "GLODAPv2.2020_clean.csv"))

2 C*

2.1 stoichiometric ratios

rCP <- 117
rNP <- 16

The stoichiometric nutrient ratios for the production and mineralization of organic matter were set to:

  • C/P: 117
  • N/P: 16

2.2 Calculation

GLODAP <- GLODAP %>% 
  mutate(rCP_phosphate = - rCP * phosphate,
         talk_05 = - 0.5 * talk,
         rNP_phosphate_05 = - 0.5 * rNP * phosphate,
         C_star = tco2 + rCP_phosphate + talk_05 + rNP_phosphate_05)

3 Selected section plots

cruises_meridional <- c("1041")

# cruises_meridional <- c("1041","1042", "260",
#                         "2011", "393", "1031", "394", "395",
#                         "1088", "983")

# cruises_zonal <- c()

GLODAP_cruise <- GLODAP %>% 
  filter(cruise %in% cruises_meridional)
mapWorld <- borders("world", colour="gray60", fill="gray60")

map <- GLODAP_cruise %>%
  ggplot(aes(longitude, latitude))+
  mapWorld+
  geom_point(aes(col=date))+
  geom_path()+
  coord_quickmap(expand = FALSE)+
  scale_color_viridis_c(trans = "date")

lat_section <- GLODAP_cruise %>%
  ggplot(aes(latitude, depth))+
  scale_y_reverse()+
  scale_color_viridis_c()

lat_tco2 <- lat_section+
  geom_point(aes(col=tco2))

lat_talk <- lat_section+
  geom_point(aes(col=talk))

lat_phosphate <- lat_section+
  geom_point(aes(col=phosphate))

lat_rCP_phosphate <- lat_section+
  geom_point(aes(col=rCP_phosphate))

lat_talk_05 <- lat_section+
  geom_point(aes(col=talk_05))

lat_rNP_phosphate_05 <- lat_section+
  geom_point(aes(col=rNP_phosphate_05))

lat_C_star <- lat_section+
  geom_point(aes(col=C_star))

map / lat_tco2 / lat_talk / lat_phosphate / lat_rCP_phosphate /lat_talk_05 /lat_rNP_phosphate_05 / lat_C_star

rm(map, lat_tco2, lat_talk, lat_phosphate, lat_C_star)

4 Reference year adjustment

The scaling factor Cant_apriori at a given location and depth was estimated for each reference year from XXX. Note that eq. 6 in Clement and Gruber (2018) misses pCO2 pre-industrial in the denominator.

GLODAP <- GLODAP %>% 
  mutate(C_star_ref = C_star - 
           ( (pCO2_atm(year) - pCO2_atm(year_ref)) / 
               (pCO2_atm(year_ref) - pCO2_atm(year_pi) ) * Cant_ref)

5 MLR fitting

temperature
salinity
phosphate
silicate
phosphate_star = phosphate + (oxygen / 170) - 1.95
oxygen
aou
basins <- c("Atlantic", "Indo_Pacific")
slabs <- c("")

for (i_basin in basins) {
  for (i_slab in slabs) {
    
    
  }
  
}

sessionInfo()
R version 3.6.3 (2020-02-29)
Platform: i386-w64-mingw32/i386 (32-bit)
Running under: Windows 10 x64 (build 18363)

Matrix products: default

locale:
[1] LC_COLLATE=English_Germany.1252  LC_CTYPE=English_Germany.1252   
[3] LC_MONETARY=English_Germany.1252 LC_NUMERIC=C                    
[5] LC_TIME=English_Germany.1252    

attached base packages:
[1] stats     graphics  grDevices utils     datasets  methods   base     

other attached packages:
 [1] patchwork_1.0.1 lubridate_1.7.9 forcats_0.5.0   stringr_1.4.0  
 [5] dplyr_1.0.0     purrr_0.3.4     readr_1.3.1     tidyr_1.1.0    
 [9] tibble_3.0.3    ggplot2_3.3.2   tidyverse_1.3.0 workflowr_1.6.2

loaded via a namespace (and not attached):
 [1] jsonlite_1.7.0    rstudioapi_0.11   generics_0.0.2    magrittr_1.5     
 [5] farver_2.0.3      gtable_0.3.0      rmarkdown_2.3     vctrs_0.3.1      
 [9] fs_1.4.2          hms_0.5.3         xml2_1.3.2        pillar_1.4.6     
[13] htmltools_0.5.0   haven_2.3.1       later_1.1.0.1     broom_0.7.0      
[17] cellranger_1.1.0  tidyselect_1.1.0  knitr_1.29        git2r_0.27.1     
[21] whisker_0.4       lifecycle_0.2.0   pkgconfig_2.0.3   R6_2.4.1         
[25] digest_0.6.25     xfun_0.15         colorspace_1.4-1  rprojroot_1.3-2  
[29] stringi_1.4.6     yaml_2.2.1        evaluate_0.14     labeling_0.3     
[33] fansi_0.4.1       httr_1.4.1        compiler_3.6.3    here_0.1         
[37] cli_2.0.2         withr_2.2.0       backports_1.1.5   munsell_0.5.0    
[41] DBI_1.1.0         modelr_0.1.8      Rcpp_1.0.5        readxl_1.3.1     
[45] dbplyr_1.4.4      maps_3.3.0        ellipsis_0.3.1    assertthat_0.2.1 
[49] blob_1.2.1        tools_3.6.3       reprex_0.3.0      viridisLite_0.3.0
[53] httpuv_1.5.4      scales_1.1.1      crayon_1.3.4      glue_1.4.1       
[57] rlang_0.4.7       rvest_0.3.5       promises_1.1.1    grid_3.6.3