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Task

This markdown file reads previously created nitrate climatology file and uses that as the definition of the depth levels that the BGC Argo nitrate data should be aligned to. Previously created BGC data (bgc_data.rds) and metadata (bgc_metadata.rds) are loaded from the BGC preprocessed folder.

Base data qc flags are checked to ensure that the float position, pressure measurements and nitrate measurements are good. Pressure is used to derive the depth of each measurement. The nitrate profile is checked to ensure that significant gaps (specified by the opt_gap_limit, opt_gap_min_depth and opt_gap_max_depth) do not exist. Profiles are assigned a profile_range field that identifies the depth 1 = 600 m, 2= 800 m.

The float nitrate profiles are then aligned using the spline function to match the depth levels of the climatology resulting in data frame bgc_data_nitrate_interpolated_clean. An anomaly file is then created from the vertically aligned profiles and climatology.

Dependencies

woa_nitrate_clim.rds - created by load_argo_clim_nitrate_woa

bgc_data, bgc_metadata - created by load_argo

Outputs (BGC preprocessed folder)

nitrate_bgc_va.rds – vertically aligned nitrate profiles.

nitrate_clim_va.rds – climatology nitrate profiles.

nitrate_anomaly_va.rds – anomaly nitrate profiles.

Set directories

location of pre-prepared data

Set options

Define options that are used to determine profiles that we will us in the ongoing analysis

# Options

# opt_profile_depth_range
# The profile must have at least one nitrate reading at a depth <= opt_profile_depth_range[1, ]
# The profile must have at least one nitrate reading at a depth >= opt_profile_depth_range[2, ].
# In addition if the profile depth does not exceed the min(opt_profile_depth_range[2, ]) (i.e. 8=600) it will be removed.
profile_range <- c(1, 2)
min_depth <- c(5.0, 5.0)
max_depth <- c(600, 800)
opt_profile_depth_range <- data.frame(profile_range, min_depth, max_depth)

# opt_gap...
# The profile should not have a gap greater that opt_gap_limit within the range defined by opt_gap_min_depth and opt_gap_max_depth
opt_gap_limit <- c(28, 55)
opt_gap_min_depth <- c(0, 400)
opt_gap_max_depth <- c(400, 800)

# opt_measure_label, opt_xlim and opt_xbreaks are associated with formatting
opt_measure_label <- expression("nitrate anomaly ( µmol kg"^"-1"~")")
opt_xlim <- c(-6, 6)
opt_xbreaks <- c(-6, -3, 0, 3, 6)

# opt_n_prof_sel
# The selection criteria that is used against n_prof, here set to 1
# Description of n_prof usage is provided at https://argo.ucsd.edu/data/data-faq/version-3-profile-files/ the next two lines are from that page.
#     The main Argo CTD profile is stored in N_PROF=1. All other parameters (including biogeochemical parameters) that are measured 
#     with the same vertical sampling scheme and at the same location and time as the main Argo CTD profile are also stored in N_PROF=1.
opt_n_prof_sel = 1

# opt_exclude_shallower
# This option will exclude depths from the climatology and subsequent vertically aligned data that are shallower than opt_exclude_shallower.
# e.g. set to 4.5 to ensure that the top depth of 0.0 m is excluded
# Set to 0.0 to ensure no depths are excluded.
opt_exclude_shallower <- 4.5

# opt_shallow_check_perc and opt_shallow_check_diff
# A check is made to ensure that the pH of the shallowest depth in the profile after vertical alignment is within a limit of the
# pH of the shallowest depth in the profile before vertical alignment
# a opt_shallow_check values of 0.01 results in those with greater than a 1% difference will be reported. Set to 0.0 if percentage check is not required.
# a opt_shallow_report_diff that is non-zero and positive will check that absolute difference. Set to 0.0 if absolute difference check is not required.  
opt_shallow_check_perc <- 0.05
opt_shallow_report_perc <- 'profile where shallow check exceeds percentage criteria: '
opt_shallow_check_diff <- 0.5
opt_shallow_report_diff <- 'profile where shallow check exceeds absolute difference criteria: '

read climatology

read nitrate climatology and prepare to a set range of depths

# climatology values (clim_nitrate (°C)) available for lat, lon, month and pressure
woa_nitrate_clim <- read_rds(file = paste0(path_argo_preprocessed, '/woa_nitrate_clim.rds'))

#What is the max depth we are interested in
opt_profile_max_depth <- max(opt_profile_depth_range$max_depth)

# what are the target depths that we align to
target_depth_levels <- woa_nitrate_clim %>% distinct(depth)

target_depth_levels <-
  target_depth_levels %>% 
  filter (depth <= opt_profile_max_depth) %>% 
  mutate(target_depth = depth) %>% 
  select(target_depth)

# select variable of interest and prepare target_depth field
woa_nitrate_clim_clean <- woa_nitrate_clim %>%
                          select(
                            lat,
                            lon,
                            month,
                            depth,
                            clim_nitrate
                          ) %>%
                          mutate(
                            target_depth = depth, .after = depth
                          )

# Exclude 0.0 m depth from the climatology and target_depth_levels
target_depth_levels <- target_depth_levels %>% 
  filter(target_depth > opt_exclude_shallower)
woa_nitrate_clim_clean <- woa_nitrate_clim_clean %>% 
  filter(depth > opt_exclude_shallower)
  
# create all possible combinations of location and month climatologies and depth levels for interpolation
target_depth_grid <-
  expand_grid(target_depth_levels,
              woa_nitrate_clim_clean %>% distinct(lat, lon, month))

# extend climatology depth vectors with target depths
woa_nitrate_clim_extended <-
  full_join(woa_nitrate_clim_clean, target_depth_grid) %>% 
  arrange(lat, lon, month, target_depth)


# filter where target depths outside range of climatology depths
# depth is slightly lower than pressure so 1.02 factor is used to ensure bottom value is not lost.
woa_nitrate_clim_extended <-
  woa_nitrate_clim_extended %>%
  group_by(lat, lon, month) %>%
  filter(
    target_depth <= max(depth, na.rm = TRUE),
    target_depth >= min(depth, na.rm = TRUE)
  ) %>%
  ungroup()

# predict spline interpolation on adjusted depth grid for climatology loaction and month
woa_nitrate_clim_interpolated <-
  woa_nitrate_clim_extended %>%
  group_by(lat, lon, month) %>%
  mutate(clim_nitrate_spline = spline(target_depth, clim_nitrate,
                                       method = "natural",
                                       xout = target_depth)$y) %>%
  ungroup()

# subset interpolated values on traget depth grid
woa_nitrate_clim_interpolated_clean <- 
  inner_join(target_depth_levels, woa_nitrate_clim_interpolated)

# select columns and rename to initial names
woa_nitrate_clim_interpolated_clean <-
  woa_nitrate_clim_interpolated_clean %>%
  select(lat, lon, month,
         depth = target_depth,
         clim_nitrate = clim_nitrate_spline)

# clean up working tables
rm(woa_nitrate_clim_clean, woa_nitrate_clim_extended, woa_nitrate_clim_interpolated)

read nitrate data

read nitrate profile and carry out basic checks, good data.

# base data and associated metadata
bgc_data <- read_rds(file = paste0(path_argo_preprocessed, '/bgc_data.rds'))
bgc_metadata <- read_rds(file = paste0(path_argo_preprocessed, '/bgc_metadata.rds'))

# Select relevant field from metadata ready to join to bgc_data
bgc_metadata_select <- bgc_metadata %>%
  filter (position_qc == 1) %>%
  select(file_id,
         date,
         lat,
         lon) %>%
  mutate(year = year(date),
         month = month(date),
         .after = date)

# we only want pressure and nitrate data
# conditions 
# n_prof == 1
# pres_adjusted_qc %in% c(1, 8) - pressure data marked as good
# nitrate_adjusted_qc %in% c(1, 8) - nitrate data marked as good
# !is.na(pres_adjusted) - pressure value must be present
# !is.na(nitrate_adjusted) - nitrate value must be present
bgc_data_nitrate <- bgc_data %>%
  filter(
    pres_adjusted_qc %in% c(1, 8) &
      nitrate_adjusted_qc %in% c(1, 8) &
      n_prof == opt_n_prof_sel &
      !is.na(pres_adjusted) &
      !is.na(nitrate_adjusted)
  ) %>%
  select(file_id,
         pres_adjusted,
         nitrate_adjusted)

# join with metadata information and calculate depth field
bgc_data_nitrate <-
  inner_join(bgc_metadata_select %>% select(file_id, lat),
             bgc_data_nitrate) %>%
  mutate(depth = gsw_z_from_p(pres_adjusted, latitude = lat) * -1.0,
         .before = pres_adjusted) %>%
  select(-c(lat, pres_adjusted))

# ensure we have a depth, and nitrate_adjusted for all rows in bgc_data_nitrate
bgc_data_nitrate <- bgc_data_nitrate %>%
  filter(!is.na(depth) & !is.na(nitrate_adjusted))

# clean up working tables
rm(bgc_data, bgc_metadata)
gc()

Profile limits

Apply the rules that are determined by options set in set_options. Profile must cover a set range and not contain gaps.

# Determine profile min and max depths
bgc_profile_limits <- bgc_data_nitrate %>%
  group_by(file_id) %>%
  summarise(
    min_depth = min(depth),
    max_depth = max(depth),
  ) %>%
  ungroup()

# --------------------------------------------------------------------------------------
# What is the distribution of min depths
# out <- bgc_profile_limits %>% 
#   filter(min_depth > 0 & min_depth < 10) %>%
#   mutate(min_bin = cut(min_depth, breaks = c(seq(0, 10, by = 0.5))))
#   
# out <- out %>%
#   group_by(min_bin) %>%
#   summarise(count_profiles = n())
# 
# out %>%
#   ggplot(aes(min_bin)) +
#   geom_bar(aes(weight = count_profiles)) +
#   scale_fill_viridis_d() +
#   labs(title = "nitrate profiles minimum depth",
#        x = "min depth (m)",
#        y = "profile count")
# 
# rm(out)
# --------------------------------------------------------------------------------------

# The profile much match at least one of teh range criteria
force_min <- min(opt_profile_depth_range$min_depth)
force_max <- min(opt_profile_depth_range$max_depth)

# Apply profile min and max restrictions
bgc_apply_limits <- bgc_profile_limits %>%
  filter(
    min_depth <= force_min &
    max_depth >= force_max
    )

# Ensure working data set only contains profiles that have conformed to the range test
bgc_data_nitrate <- right_join(bgc_data_nitrate,
                            bgc_apply_limits %>% select(file_id))

# Add profile type field and set all to 1.  
# All profile that meet the minimum requirements are profile_range = 1
bgc_data_nitrate <- bgc_data_nitrate %>%
  mutate(profile_range = 1)

for (i in 2:nrow(opt_profile_depth_range)) {

  #i = 3
  range_min <- opt_profile_depth_range[i,'min_depth']
  range_max <- opt_profile_depth_range[i,'max_depth']

  # Apply profile min and max restrictions
  bgc_apply_limits <- bgc_profile_limits %>%
    filter(min_depth <= range_min &
             max_depth >= range_max) %>%
    select(file_id) %>%
    mutate (profile_range = i)

  # Update profile range to i for these profiles
  # bgc_data_nitrate <- full_join(bgc_data_nitrate, bgc_apply_limits) %>%
  #                         filter(!is.na(min_depth))
  bgc_data_nitrate <-
    bgc_data_nitrate %>% rows_update(bgc_apply_limits, by = "file_id")

}

# Find the gaps within the profiles
profile_gaps <- full_join(bgc_data_nitrate,
                          opt_profile_depth_range) %>%
  filter(depth >= min_depth & 
           depth <= max_depth) %>% 
  select(file_id,
         depth) %>%
  arrange(file_id, depth) %>%
  group_by(file_id) %>%
  mutate(gap = depth - lag(depth, default = 0)) %>%
  ungroup()

# Ensure we do not have gaps in the profile that invalidate it 
for (i_gap in opt_gap_limit) {

  # The limits to be applied in that pass of for loop
  # i_gap <- opt_gap_limit[3]
  i_gap_min = opt_gap_min_depth[which(opt_gap_limit == i_gap)]
  i_gap_max = opt_gap_max_depth[which(opt_gap_limit == i_gap)]
  
  # Which gaps are greater than i_gap
  profile_gaps_remove <- profile_gaps %>%
    filter(gap > i_gap) %>%
    filter(depth >= i_gap_min & depth <= i_gap_max) %>%
    distinct(file_id) %>% 
    pull()
  
  # Remonve gap-containing profiles from working data set
  bgc_data_nitrate <- bgc_data_nitrate %>% 
    filter(!file_id %in% profile_gaps_remove)
}

# clean up working tables
rm(bgc_profile_limits, profile_gaps, profile_gaps_remove, bgc_apply_limits)
gc()

# For each profile what is the nitrate at the shallowest depth of the profile, this is used in a comparison after vertical alignment
shallow_nitrate_raw <- right_join(
  bgc_data_nitrate,
  bgc_data_nitrate %>%
    group_by(file_id) %>%
    summarise(depth = min(depth)) %>%
    ungroup()
) %>%
  select (file_id, nitrate_shallow_raw = nitrate_adjusted)


# Write file that are observations prior to vertical alignment 
bgc_data_nitrate_full <- left_join(bgc_data_nitrate, bgc_metadata_select)

# bgc_data_nitrate_full %>%
#   select(file_id, lat, lon, date, year, month, depth, nitrate_adjusted) %>%
#   write_rds(file = paste0(path_argo_preprocessed, "/nitrate_bgc_observed.rds"))

rm(bgc_data_nitrate_full)
gc()

Vertical align nitrate

We have a set of nitrate profiles that match our criteria we now need to align that data set to match the depth that are in target_depth_levels, this will match the range of climatology values in woa_nitrate_clim_interpolated_clean

# create unique combinations of file_id and profile ranges
profile_range_file_id <- 
  bgc_data_nitrate %>% 
  distinct(file_id, profile_range)


# select variable of interest and prepare target_depth field
bgc_data_nitrate_clean <- bgc_data_nitrate %>%
  select(-profile_range) %>%
  mutate(target_depth = depth, .after = depth)

rm(bgc_data_nitrate)
gc()

# create all possible combinations of location, month and depth levels for interpolation
target_depth_grid <-
  expand_grid(
    target_depth_levels,
    profile_range_file_id
  )

# Constrain target_depth_grid to profile depth range
target_depth_grid <-
  left_join(target_depth_grid, opt_profile_depth_range) %>%
  filter(target_depth <= max_depth)

target_depth_grid <- target_depth_grid %>%
  select(target_depth,
         file_id)

# extend nitrate depth vectors with target depths
bgc_data_nitrate_extended <-
  full_join(bgc_data_nitrate_clean, target_depth_grid) %>%
  arrange(file_id, target_depth)

rm(bgc_data_nitrate_clean)
gc()

# predict spline interpolation on adjusted depth grid for nitrate location and month
bgc_data_nitrate_interpolated <-
  bgc_data_nitrate_extended %>%
  group_by(file_id) %>%
  mutate(nitrate_spline = spline(target_depth, nitrate_adjusted,
                                method = "natural",
                                xout = target_depth)$y) %>%
  ungroup()

rm(bgc_data_nitrate_extended)
gc()

# subset interpolated values on target depth range
bgc_data_nitrate_interpolated_clean <- 
  inner_join(target_depth_levels, bgc_data_nitrate_interpolated)

rm(bgc_data_nitrate_interpolated)
gc()

# select columns and rename to initial names
bgc_data_nitrate_interpolated_clean <-
  bgc_data_nitrate_interpolated_clean %>%
  select(file_id,
         depth = target_depth,
         nitrate = nitrate_spline)

# merge with profile range
bgc_data_nitrate_interpolated_clean <-
  full_join(bgc_data_nitrate_interpolated_clean,
            profile_range_file_id)

# merge with meta data
bgc_data_nitrate_interpolated_clean <-
  left_join(bgc_data_nitrate_interpolated_clean,
            bgc_metadata_select)

# For each profile what is the nitrate at the shallowest depth of the profile after vertical alignment
shallow_nitrate_va <- right_join(
  bgc_data_nitrate_interpolated_clean,
  bgc_data_nitrate_interpolated_clean %>%
    group_by(file_id) %>%
    summarise(depth = min(depth)) %>% 
    ungroup()
) %>%
  select (file_id, nitrate_shallow_va = nitrate)

Check shallow

A check is made that the shallowest nitrate value after the vertical alignment is within a specified percentage of the shallowest nitrate value before the vertical alignment

# Combined dataframe with shallow value pre and post vertical alignment
shallow_nitrate_check <- 
  full_join(shallow_nitrate_raw, shallow_nitrate_va)

# Determine those profile that are outside of percentage criteria.
if (opt_shallow_check_perc > 0.0){
  shallow_check_report <- shallow_nitrate_check %>%
    filter (abs((nitrate_shallow_raw - nitrate_shallow_va) / nitrate_shallow_raw) > opt_shallow_check_perc)

  # Write issues to console
  if (nrow(shallow_check_report) > 0) {
    print (opt_shallow_report_perc)
    shallow_check_report %>% rmarkdown::paged_table()
  }
}

# Determine those profile that are outside of absolute difference criteria.
if (opt_shallow_check_diff > 0.0){
  shallow_check_report <- shallow_nitrate_check %>%
    filter (abs(nitrate_shallow_raw - nitrate_shallow_va) > opt_shallow_check_diff)

  # Write issues to console
  if (nrow(shallow_check_report) > 0) {
    print (opt_shallow_report_diff)
    shallow_check_report %>% rmarkdown::paged_table()
  }
}


# remove working files
rm(shallow_nitrate_check, shallow_nitrate_raw, shallow_nitrate_va, shallow_check_report)
gc()

Create anomaly profiles

Create anomaly profiles as observed - climatology

# Create bgc_nitrate_anomaly, but only where we have an climatology nitrate
bgc_nitrate_anomaly <-
  inner_join(bgc_data_nitrate_interpolated_clean, woa_nitrate_clim_interpolated_clean)

# Calculate the anomaly nitrate
bgc_nitrate_anomaly <- bgc_nitrate_anomaly %>%
                      mutate(
                        anomaly = nitrate - clim_nitrate
                      )

# -----------------------------------------------------------------------------
# Climatology check
# -----------------------------------------------------------------------------
# It is possible even though we have observational measures to full depth the climatology may not matach all depth.
# These profiles will be removed from both nitrate_bgc_va and nitrate_anomaly_va

# Anomaly max depth
bgc_nitrate_anomaly_depth_check <- bgc_nitrate_anomaly %>%
  group_by(file_id,
           profile_range) %>%
  summarise(min_pdepth = min(depth),
            max_pdepth = max(depth)) %>%
  ungroup()

# Add the required min depth and max depth
bgc_nitrate_anomaly_depth_check <- left_join(bgc_nitrate_anomaly_depth_check, opt_profile_depth_range)

# This profiles do not match the depth required by the profile_range
# min_depth_check <- min(target_depth_grid$target_depth)

# Please double check if the criterion should be
# each profile is checked against the min depth specified in min_depth 
# max depth specified in max_depth. 
remove_profiles <- bgc_nitrate_anomaly_depth_check %>%
  filter((max_pdepth < max_depth) | (min_pdepth > min_depth)) %>%
  distinct(file_id)

# remove from both bgc_data_nitrate_interpolated_clean and bgc_nitrate_anomaly
bgc_data_nitrate_interpolated_clean <-
  anti_join(bgc_data_nitrate_interpolated_clean, remove_profiles)

bgc_nitrate_anomaly <- anti_join(bgc_nitrate_anomaly, remove_profiles)

Write files

Write the climatology that maps onto depth levels, interpolated nitrate profiles that map onto depth levels and resulting anomaly files.

# Write files
bgc_data_nitrate_interpolated_clean %>%
  write_rds(file = paste0(path_argo_preprocessed, "/nitrate_bgc_va.rds"))

woa_nitrate_clim_interpolated_clean %>%
  write_rds(file = paste0(path_argo_preprocessed, "/nitrate_clim_va.rds"))

bgc_nitrate_anomaly %>%
  write_rds(file = paste0(path_argo_preprocessed, "/nitrate_anomaly_va.rds"))

# Rename so that names match if just reading existing files
nitrate_bgc_va <- bgc_data_nitrate_interpolated_clean
nitrate_clim_va <- woa_nitrate_clim_interpolated_clean
nitrate_anomaly_va <- bgc_nitrate_anomaly

#rm(bgc_data_nitrate_interpolated_clean, woa_nitrate_clim_interpolated_clean, bgc_nitrate_anomaly)

read files

Read files that were previously created ready for analysis

# read files
nitrate_bgc_va <- read_rds(file = paste0(path_argo_preprocessed, "/nitrate_bgc_va.rds"))

nitrate_clim_va <- read_rds(file = paste0(path_argo_preprocessed, "/nitrate_clim_va.rds"))

nitrate_anomaly_va <- read_rds(file = paste0(path_argo_preprocessed, "/nitrate_anomaly_va.rds"))

Analysis

nitrate anomaly

Details of mean anomaly over analysis period

max_depth_1 <- opt_profile_depth_range[1, "max_depth"]
max_depth_2 <- opt_profile_depth_range[2, "max_depth"]

# Profiles to 600m
anomaly_overall_mean_1 <- nitrate_anomaly_va %>% 
  filter(profile_range %in% c(1, 2) & depth <= max_depth_1) %>%
  group_by(depth) %>% 
  summarise(nitrate_count = n(),
            nitrate_anomaly_mean = mean(anomaly, na.rm = TRUE),
            nitrate_anomaly_sd = sd(anomaly, na.rm = TRUE))

anomaly_year_mean_1 <- nitrate_anomaly_va %>% 
  filter(profile_range %in% c(1, 2) & depth <= max_depth_1) %>%
  group_by(year, depth) %>% 
  summarise(nitrate_count = n(),
            nitrate_anomaly_mean = mean(anomaly, na.rm = TRUE),
            nitrate_anomaly_sd = sd(anomaly, na.rm = TRUE))

# Profiles to 900m
anomaly_overall_mean_2 <- nitrate_anomaly_va %>% 
  filter(profile_range %in% c(2) & depth <= max_depth_2) %>%
  group_by(depth) %>% 
  summarise(nitrate_count = n(),
            nitrate_anomaly_mean = mean(anomaly, na.rm = TRUE),
            nitrate_anomaly_sd = sd(anomaly, na.rm = TRUE))

anomaly_year_mean_2 <- nitrate_anomaly_va %>% 
  filter(profile_range %in% c(2) & depth <= max_depth_2) %>%
  group_by(year, depth) %>% 
  summarise(nitrate_count = n(),
            nitrate_anomaly_mean = mean(anomaly, na.rm = TRUE),
            nitrate_anomaly_sd = sd(anomaly, na.rm = TRUE))

# All years anomaly
anomaly_overall_mean_1 %>% 
  ggplot()+
  geom_path(aes(x = nitrate_anomaly_mean,
                y = depth))+
  geom_ribbon(aes(xmax = nitrate_anomaly_mean + nitrate_anomaly_sd,
                  xmin = nitrate_anomaly_mean - nitrate_anomaly_sd,
                  y = depth),
              alpha = 0.2)+
  geom_vline(xintercept = 0)+
  scale_y_reverse() +
  coord_cartesian(xlim = opt_xlim) +
  scale_x_continuous(breaks = opt_xbreaks) +
  labs(
    title = paste0('Overall mean anomaly profiles to ', max_depth_1, 'm'),
    x = opt_measure_label,
    y = 'depth (m)'
  )

Version	Author	Date
c076fba	mlarriere	2024-04-12
f9de50e	ds2n19	2024-01-01
fa6cf38	ds2n19	2023-12-14

anomaly_overall_mean_2 %>% 
  ggplot()+
  geom_path(aes(x = nitrate_anomaly_mean,
                y = depth))+
  geom_ribbon(aes(xmax = nitrate_anomaly_mean + nitrate_anomaly_sd,
                  xmin = nitrate_anomaly_mean - nitrate_anomaly_sd,
                  y = depth),
              alpha = 0.2)+
  geom_vline(xintercept = 0)+
  scale_y_reverse() +
  coord_cartesian(xlim = opt_xlim) +
  scale_x_continuous(breaks = opt_xbreaks) +
  labs(
    title = paste0('Overall mean anomaly profiles to ', max_depth_2, 'm'),
    x = opt_measure_label,
    y = 'depth (m)'
  )

Version	Author	Date
c076fba	mlarriere	2024-04-12
f9de50e	ds2n19	2024-01-01
fa6cf38	ds2n19	2023-12-14

# yearly anomaly
anomaly_year_mean_1 %>% 
  ggplot()+
  geom_path(aes(x = nitrate_anomaly_mean,
                y = depth))+
  geom_ribbon(aes(xmax = nitrate_anomaly_mean + nitrate_anomaly_sd,
                  xmin = nitrate_anomaly_mean - nitrate_anomaly_sd,
                  y = depth),
              alpha = 0.2)+
  geom_vline(xintercept = 0)+
  scale_y_reverse() +
  facet_wrap(~year)+
  coord_cartesian(xlim = opt_xlim) +
  scale_x_continuous(breaks = opt_xbreaks) +
  labs(
    title = paste0('Yearly mean anomaly profiles to ', max_depth_1, 'm'),
    x = opt_measure_label,
    y = 'depth (m)'
  )

Version	Author	Date
c076fba	mlarriere	2024-04-12
f9de50e	ds2n19	2024-01-01
fa6cf38	ds2n19	2023-12-14

anomaly_year_mean_2 %>% 
  ggplot()+
  geom_path(aes(x = nitrate_anomaly_mean,
                y = depth))+
  geom_ribbon(aes(xmax = nitrate_anomaly_mean + nitrate_anomaly_sd,
                  xmin = nitrate_anomaly_mean - nitrate_anomaly_sd,
                  y = depth),
              alpha = 0.2)+
  geom_vline(xintercept = 0)+
  scale_y_reverse() +
  facet_wrap(~year)+
  coord_cartesian(xlim = opt_xlim) +
  scale_x_continuous(breaks = opt_xbreaks) +
  labs(
    title = paste0('Yearly mean anomaly profiles to ', max_depth_2, 'm'),
    x = opt_measure_label,
    y = 'depth (m)'
  )

Version	Author	Date
c076fba	mlarriere	2024-04-12
f9de50e	ds2n19	2024-01-01
fa6cf38	ds2n19	2023-12-14

#rm(anomaly_overall_mean)

Profile counts

Details of the number of profiles and to which depths over the analysis period

nitrate_histogram <- nitrate_bgc_va %>%
  group_by(year, profile_range = as.character(profile_range)) %>%
  summarise(num_profiles = n_distinct(file_id)) %>%
  ungroup()

nitrate_histogram %>%
  ggplot() +
  geom_bar(
    aes(
      x = year,
      y = num_profiles,
      fill = profile_range,
      group = profile_range
    ),
    position = "stack",
    stat = "identity"
  ) +
  scale_fill_viridis_d() +
  labs(title = "nitrate profiles per year and profile range",
       x = "year",
       y = "profile count",
       fill = "profile range")

Version	Author	Date
c076fba	mlarriere	2024-04-12
f9de50e	ds2n19	2024-01-01
fa6cf38	ds2n19	2023-12-14

sessionInfo()

R version 4.2.2 (2022-10-31)
Platform: x86_64-pc-linux-gnu (64-bit)
Running under: openSUSE Leap 15.5

Matrix products: default
BLAS:   /usr/local/R-4.2.2/lib64/R/lib/libRblas.so
LAPACK: /usr/local/R-4.2.2/lib64/R/lib/libRlapack.so

locale:
 [1] LC_CTYPE=en_US.UTF-8       LC_NUMERIC=C              
 [3] LC_TIME=en_US.UTF-8        LC_COLLATE=en_US.UTF-8    
 [5] LC_MONETARY=en_US.UTF-8    LC_MESSAGES=en_US.UTF-8   
 [7] LC_PAPER=en_US.UTF-8       LC_NAME=C                 
 [9] LC_ADDRESS=C               LC_TELEPHONE=C            
[11] LC_MEASUREMENT=en_US.UTF-8 LC_IDENTIFICATION=C       

attached base packages:
[1] stats     graphics  grDevices utils     datasets  methods   base     

other attached packages:
 [1] ggforce_0.4.1    gsw_1.1-1        gridExtra_2.3    lubridate_1.9.0 
 [5] timechange_0.1.1 argodata_0.1.0   forcats_0.5.2    stringr_1.5.0   
 [9] dplyr_1.1.3      purrr_1.0.2      readr_2.1.3      tidyr_1.3.0     
[13] tibble_3.2.1     ggplot2_3.4.4    tidyverse_1.3.2 

loaded via a namespace (and not attached):
 [1] httr_1.4.4          sass_0.4.4          viridisLite_0.4.1  
 [4] jsonlite_1.8.3      modelr_0.1.10       bslib_0.4.1        
 [7] assertthat_0.2.1    highr_0.9           googlesheets4_1.0.1
[10] cellranger_1.1.0    yaml_2.3.6          pillar_1.9.0       
[13] backports_1.4.1     glue_1.6.2          digest_0.6.30      
[16] promises_1.2.0.1    polyclip_1.10-4     rvest_1.0.3        
[19] colorspace_2.0-3    htmltools_0.5.8.1   httpuv_1.6.6       
[22] pkgconfig_2.0.3     broom_1.0.5         haven_2.5.1        
[25] scales_1.2.1        tweenr_2.0.2        whisker_0.4        
[28] later_1.3.0         tzdb_0.3.0          git2r_0.30.1       
[31] googledrive_2.0.0   generics_0.1.3      farver_2.1.1       
[34] ellipsis_0.3.2      cachem_1.0.6        withr_2.5.0        
[37] cli_3.6.1           magrittr_2.0.3      crayon_1.5.2       
[40] readxl_1.4.1        evaluate_0.18       fs_1.5.2           
[43] fansi_1.0.3         MASS_7.3-58.1       xml2_1.3.3         
[46] tools_4.2.2         hms_1.1.2           gargle_1.2.1       
[49] lifecycle_1.0.3     munsell_0.5.0       reprex_2.0.2       
[52] compiler_4.2.2      jquerylib_0.1.4     RNetCDF_2.6-1      
[55] rlang_1.1.1         grid_4.2.2          rstudioapi_0.15.0  
[58] labeling_0.4.2      rmarkdown_2.18      gtable_0.3.1       
[61] DBI_1.2.2           R6_2.5.1            knitr_1.41         
[64] fastmap_1.1.0       utf8_1.2.2          workflowr_1.7.0    
[67] rprojroot_2.0.3     stringi_1.7.8       Rcpp_1.0.10        
[70] vctrs_0.6.4         dbplyr_2.2.1        tidyselect_1.2.0   
[73] xfun_0.35

Prepare nitrate data and vertically align to climatology

David Stappard & Jens Daniel Müller

12 April, 2024