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path_sabine_2004    <- "/nfs/kryo/work/updata/glodapv1_1/GLODAP_gridded.data/"
path_preprocessing  <- paste(path_root, "/observations/preprocessing/", sep = "")
library(marelac)

1 Data source

2 Read nc files

# read text files
AnthCO2_data <-
  read_csv(
    paste(path_sabine_2004,
          "AnthCO2.data/AnthCO2.data.txt",
          sep = ""),
    col_names = FALSE,
    na = "-999",
    col_types = list(.default = "d")
  )

# read respective depth layers and convert to vector
Depth_centers <-
  read_file(paste(path_sabine_2004,
                  "Depth.centers.txt",
                  sep = ""))

Depth_centers <- Depth_centers %>%
  str_split(",") %>%
  as_vector()

# read respective latitudes and convert to vector
Lat_centers <-
  read_file(paste(path_sabine_2004, "Lat.centers.txt",
                  sep = ""))

Lat_centers <- Lat_centers %>%
  str_split(",") %>%
  as_vector()

# read respective longitudes and convert to vector
Long_centers <-
  read_file(paste(path_sabine_2004, "Long.centers.txt",
                  sep = ""))

Long_centers <- Long_centers %>%
  str_split(",") %>%
  as_vector()

# match lon, lat and depth vectors with Cant value file
names(AnthCO2_data) <- Lat_centers

Long_Depth <-
  expand_grid(depth = Depth_centers, lon = Long_centers) %>%
  mutate(lon = as.numeric(lon),
         depth = as.numeric(depth))

tcant_3d <- bind_cols(AnthCO2_data, Long_Depth)

# adjust file dimensions
tcant_3d <- tcant_3d %>%
  pivot_longer(1:180, names_to = "lat", values_to = "tcant") %>%
  mutate(lat = as.numeric(lat))

tcant_3d <- tcant_3d %>%
  drop_na()

# harmonize coordinates
tcant_3d <- tcant_3d %>%
  mutate(lon = if_else(lon < 20, lon + 360, lon))

rm(AnthCO2_data,
   Long_Depth,
   Depth_centers,
   Lat_centers,
   Long_centers)

3 Apply basin mask

# use only three basin to assign general basin mask
# ie this is not specific to the MLR fitting
basinmask <- basinmask %>% 
  filter(MLR_basins == "2") %>% 
  select(lat, lon, basin_AIP)

tcant_3d <- inner_join(tcant_3d, basinmask)

4 Calculation

4.1 Column inventory

tcant_3d <- tcant_3d %>% 
  mutate(tcant_pos = if_else(tcant <= 0, 0, tcant))

tcant_inv_layers <- m_tcant_inv(tcant_3d)

tcant_inv <- tcant_inv_layers %>% 
  filter(inv_depth == params_global$inventory_depth_standard)

4.2 Zonal mean section

tcant_zonal <- m_zonal_mean_sd(tcant_3d)
m_dcant_budget(
  tcant_inv_layers %>%
    rename(dcant = tcant,
           dcant_pos = tcant_pos) %>%
    mutate(method = "total",
           data_source = "obs")) %>%
  select(-c(data_source, method)) %>% 
  group_by(estimate) %>%
  mutate(ratio = round(value / lag(value),3)) %>%
  ungroup() %>% 
  arrange(estimate, inv_depth)
# A tibble: 10 × 4
   inv_depth estimate  value  ratio
       <dbl> <chr>     <dbl>  <dbl>
 1       100 dcant      16.8 NA    
 2       500 dcant      63.0  3.75 
 3      1000 dcant      87.9  1.39 
 4      3000 dcant     102.   1.16 
 5     10000 dcant      97.7  0.963
 6       100 dcant_pos  16.8 NA    
 7       500 dcant_pos  63.0  3.75 
 8      1000 dcant_pos  88.2  1.40 
 9      3000 dcant_pos 104.   1.18 
10     10000 dcant_pos 106.   1.02 

5 Plots

5.1 Inventory map

p_map_cant_inv(
  df = tcant_inv,
  var = "tcant_pos",
  breaks = seq(0,max(tcant_inv$tcant_pos),5))

Version Author Date
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f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
0908ee5 jens-daniel-mueller 2021-11-15
58bc706 jens-daniel-mueller 2021-07-06

5.2 Horizontal plane maps

p_map_climatology(
  df = tcant_3d,
  var = "tcant",
  col = "divergent")

Version Author Date
aea9afe jens-daniel-mueller 2022-04-07
dde77eb jens-daniel-mueller 2022-04-01
0908ee5 jens-daniel-mueller 2021-11-15
58bc706 jens-daniel-mueller 2021-07-06

5.3 Global section

p_section_global(
  df = tcant_3d,
  var = "tcant",
  col = "divergent")

Version Author Date
f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
58bc706 jens-daniel-mueller 2021-07-06

5.4 Sections at regular longitudes

p_section_climatology_regular(
  df = tcant_3d,
  var = "tcant",
  col = "divergent")

Version Author Date
aea9afe jens-daniel-mueller 2022-04-07
f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
58bc706 jens-daniel-mueller 2021-07-06

5.5 Write files

tcant_3d %>%
  write_csv(paste(path_preprocessing,
                  "S04_tcant_3d.csv", sep = ""))

tcant_inv %>%
  write_csv(paste(path_preprocessing,
                  "S04_tcant_inv.csv", sep = ""))

tcant_zonal %>%
  write_csv(paste(path_preprocessing,
                  "S04_tcant_zonal.csv", sep = ""))

6 Anomalous changes

tcant_inv_S04 <- tcant_inv

dcant_inv_G19 <- read_csv(paste(path_preprocessing,
                               "G19_dcant_inv.csv", sep = ""))

7 Comparison of previous estimates

Cant inventory estimates of S04 (Sabine et al, 2004) and G19 (Gruber et al, 2019) were compared.

7.1 Merge data sets

cant_inv <- full_join(dcant_inv_G19 %>%
                        mutate(estimate = "G19") %>% 
                        rename(cant_pos = dcant_pos) %>% 
                        select(-dcant),
                      tcant_inv_S04 %>% 
                        mutate(estimate = "S04") %>% 
                        rename(cant_pos = tcant_pos) %>% 
                        select(-tcant))

rm(dcant_inv_G19, tcant_inv_S04)

7.2 Inventory maps

Spanning different time periods, the Cant inventories differ in magnitude. Please note, that we refer to cant_pos here, but strictly speaking we compare dcant and tcant.

map +
  geom_raster(data = cant_inv,
              aes(lon, lat, fill = cant_pos)) +
  scale_fill_viridis_c() +
  facet_wrap( ~ estimate, ncol = 1) +
  theme(
    axis.title = element_blank(),
    axis.text = element_blank(),
    axis.ticks = element_blank()
  )

Version Author Date
aea9afe jens-daniel-mueller 2022-04-07
f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
6312bd4 jens-daniel-mueller 2021-07-07

7.3 Cant budgets

Global Cant inventories were estimated in Pg-C. Please note that here we only added positive Cant values in the upper m and do not apply additional corrections for areas not covered.

cant_inv <- cant_inv %>% 
  mutate(surface_area = earth_surf(lat, lon),
         cant_pos_grid = cant_pos*surface_area)

cant_inv_budget <- cant_inv %>% 
  group_by(estimate, basin_AIP) %>% 
  summarise(cant_pos_total = sum(cant_pos_grid)*12*1e-15,
            cant_pos_total = round(cant_pos_total,1)) %>% 
  ungroup() %>% 
  pivot_wider(values_from = cant_pos_total, names_from = basin_AIP) %>% 
  mutate(total = Atlantic + Indian + Pacific)

cant_inv_budget
# A tibble: 2 × 5
  estimate Atlantic Indian Pacific total
  <chr>       <dbl>  <dbl>   <dbl> <dbl>
1 G19          11      7.1    13.4  31.5
2 S04          39.6   23.4    41.4 104. 

7.4 Relative inventories

cant_inv_wide <- cant_inv %>%
  pivot_wider(values_from = c(cant_pos, cant_pos_grid),
              names_from = estimate)

cant_inv_wide <- cant_inv_wide %>% 
  drop_na() %>% 
  mutate(G19_rel = cant_pos_grid_G19 / sum(cant_pos_grid_G19),
         S04_rel = cant_pos_grid_S04 / sum(cant_pos_grid_S04),
         cant_ratio_rel = G19_rel / S04_rel)

cant_inv_rel <- cant_inv_wide %>%
  pivot_longer(
    cols = c(G19_rel, S04_rel),
    names_to = "estimate",
    values_to = "cant_pos_rel"
  )
map +
  geom_raster(data = cant_inv_rel,
              aes(lon, lat, fill = cant_pos_rel*100)) +
  scale_fill_viridis_c() +
  facet_wrap( ~ estimate, ncol = 1) +
  theme(
    axis.title = element_blank(),
    axis.text = element_blank(),
    axis.ticks = element_blank()
  )

Version Author Date
aea9afe jens-daniel-mueller 2022-04-07
f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
6312bd4 jens-daniel-mueller 2021-07-07

7.5 Relative inventory ratios

map +
  geom_contour_filled(data = cant_inv_wide %>%
  filter(cant_ratio_rel < 10,
         cant_ratio_rel > 0.1),
                      aes(lon, lat, z = log10(cant_ratio_rel))) +
  coord_quickmap(expand = 0) +
  scale_fill_brewer(palette = "RdBu", direction = -1) +
  labs(title = "Cant inventory distribution | 1994-2007 vs preind-1994",
       subtitle = "Log ratio of relative contributions to total inventory") +
  theme(
    axis.title = element_blank(),
    axis.text = element_blank(),
    axis.ticks = element_blank(),
    legend.title = element_blank()
  )

Version Author Date
aea9afe jens-daniel-mueller 2022-04-07
f088f55 jens-daniel-mueller 2022-04-01
dde77eb jens-daniel-mueller 2022-04-01
6312bd4 jens-daniel-mueller 2021-07-07

sessionInfo()
R version 4.1.2 (2021-11-01)
Platform: x86_64-pc-linux-gnu (64-bit)
Running under: openSUSE Leap 15.3

Matrix products: default
BLAS:   /usr/local/R-4.1.2/lib64/R/lib/libRblas.so
LAPACK: /usr/local/R-4.1.2/lib64/R/lib/libRlapack.so

locale:
 [1] LC_CTYPE=en_US.UTF-8       LC_NUMERIC=C              
 [3] LC_TIME=en_US.UTF-8        LC_COLLATE=en_US.UTF-8    
 [5] LC_MONETARY=en_US.UTF-8    LC_MESSAGES=en_US.UTF-8   
 [7] LC_PAPER=en_US.UTF-8       LC_NAME=C                 
 [9] LC_ADDRESS=C               LC_TELEPHONE=C            
[11] LC_MEASUREMENT=en_US.UTF-8 LC_IDENTIFICATION=C       

attached base packages:
[1] stats     graphics  grDevices utils     datasets  methods   base     

other attached packages:
 [1] colorspace_2.0-2 marelac_2.1.10   shape_1.4.6      ggforce_0.3.3   
 [5] metR_0.11.0      scico_1.3.0      patchwork_1.1.1  collapse_1.7.0  
 [9] forcats_0.5.1    stringr_1.4.0    dplyr_1.0.7      purrr_0.3.4     
[13] readr_2.1.1      tidyr_1.1.4      tibble_3.1.6     ggplot2_3.3.5   
[17] tidyverse_1.3.1  workflowr_1.7.0 

loaded via a namespace (and not attached):
 [1] fs_1.5.2           bit64_4.0.5        lubridate_1.8.0    gsw_1.0-6         
 [5] RColorBrewer_1.1-2 httr_1.4.2         rprojroot_2.0.2    tools_4.1.2       
 [9] backports_1.4.1    bslib_0.3.1        utf8_1.2.2         R6_2.5.1          
[13] DBI_1.1.2          withr_2.4.3        tidyselect_1.1.1   processx_3.5.2    
[17] bit_4.0.4          compiler_4.1.2     git2r_0.29.0       cli_3.1.1         
[21] rvest_1.0.2        xml2_1.3.3         isoband_0.2.5      labeling_0.4.2    
[25] sass_0.4.0         scales_1.1.1       checkmate_2.0.0    SolveSAPHE_2.1.0  
[29] callr_3.7.0        digest_0.6.29      rmarkdown_2.11     oce_1.5-0         
[33] pkgconfig_2.0.3    htmltools_0.5.2    highr_0.9          dbplyr_2.1.1      
[37] fastmap_1.1.0      rlang_0.4.12       readxl_1.3.1       rstudioapi_0.13   
[41] jquerylib_0.1.4    generics_0.1.1     farver_2.1.0       jsonlite_1.7.3    
[45] vroom_1.5.7        magrittr_2.0.1     Rcpp_1.0.8         munsell_0.5.0     
[49] fansi_1.0.2        lifecycle_1.0.1    stringi_1.7.6      whisker_0.4       
[53] yaml_2.2.1         MASS_7.3-55        grid_4.1.2         parallel_4.1.2    
[57] promises_1.2.0.1   crayon_1.4.2       haven_2.4.3        hms_1.1.1         
[61] seacarb_3.3.0      knitr_1.37         ps_1.6.0           pillar_1.6.4      
[65] reprex_2.0.1       glue_1.6.0         evaluate_0.14      getPass_0.2-2     
[69] data.table_1.14.2  modelr_0.1.8       vctrs_0.3.8        tzdb_0.2.0        
[73] tweenr_1.0.2       httpuv_1.6.5       cellranger_1.1.0   gtable_0.3.0      
[77] polyclip_1.10-0    assertthat_0.2.1   xfun_0.29          broom_0.7.11      
[81] later_1.3.0        viridisLite_0.4.0  ellipsis_0.3.2