eMLR - data preparation
Jens Daniel Müller
10 November, 2020
Last updated: 2020-11-10
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Knit directory: Cant_eMLR/
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library(tidyverse)
library(lubridate)
library(patchwork)
library(marelac)1 Required data
Required are:
- GLODAPv2.2020
- cleaned data file
- horizontal grid of sampling coordinates
- Cant from GLODAPv2_2016b_MappedClimatologies
- annual mean atmospheric pCO2
GLODAP <-
read_csv(
here::here(
"data/GLODAPv2_2020/_summarized_data_files",
"GLODAPv2.2020_clean.csv"
)
)
GLODAP_obs_grid <-
read_csv(
here::here(
"data/GLODAPv2_2020/_summarized_data_files",
"GLODAPv2.2020_clean_obs_grid.csv"
)
)
Cant_clim <-
read_csv(
here::here(
"data/GLODAPv2_2016b_MappedClimatologies/_summarized_files",
"Cant.csv"
)
)
co2_atm <-
read_csv(here::here(
"data/pCO2_atmosphere/_summarized_data_files",
"co2_atm.csv"
))Cant_clim <- Cant_clim %>%
rename(cant = Cant)2 C*
C* serves as a conservative tracer of anthropogenic CO2 uptake. It is derived from measured DIC by removing the impact of
- organic matter formation and respiration
- calcification and calcium carbonate dissolution
Contributions of those processes are estimated from phosphate and alkalinity concentrations.
2.1 Stoichiometric ratios
rCP <- 117
rNP <- 16The stoichiometric nutrient ratios for the production and mineralization of organic matter were set to:
- C/P: 117
- N/P: 16
2.2 Calculation
C* is calculated as:
print("Cstar = tco2 + rCP_phosphate + talk_05 + rNP_phosphate_05")[1] "Cstar = tco2 + rCP_phosphate + talk_05 + rNP_phosphate_05"GLODAP <- GLODAP %>%
mutate(rCP_phosphate = -rCP * phosphate,
talk_05 = -0.5 * talk,
rNP_phosphate_05 = -0.5 * rNP * phosphate,
Cstar = tco2 + rCP_phosphate + talk_05 + rNP_phosphate_05)
rm(rCP, rNP)3 PO4* calculation
The predictor PO4* was be calculated according to Clement and Gruber (2018), ie based on oxygen. Please note that an errornous equations for PO4* calculation is given in the supplement of Gruber et al (2019), based on nitrate.
GLODAP <- GLODAP %>%
mutate(phosphate_star = phosphate + (oxygen / 170) - 1.95)4 Reference year adjustment
The reference year adjustment relies on an apriori estimate of Cant at a given location and depth, which is used as a scaling factor for the concurrent change in atmospheric CO2. The underlying assumption is a transient steady state for the oceanic Cant uptake. Here, Cant from the GLODAP mapped Climatology was used.
Note that eq. 6 in Clement and Gruber (2018) misses pCO2 pre-industrial in the denominator. Here we use the equation published in Gruber et al. (2019).
4.1 Merge data sets
4.1.1 GLODAP + Cant
Cant_clim_obs <- left_join(GLODAP_obs_grid, Cant_clim)
Cant_clim_obs <- Cant_clim_obs %>%
group_by(lon, lat) %>%
mutate(n = n()) %>%
ungroup()
# Cant_clim_obs %>%
# filter(n <= 1) %>%
# ggplot(aes(lon,lat)) +
# geom_point(data = GLODAP_obs_grid, aes(lon, lat)) +
# geom_point(col = "red")
rm(Cant_clim, GLODAP_obs_grid)
GLODAP_Cant_obs <- full_join(GLODAP, Cant_clim_obs)
rm(GLODAP, Cant_clim_obs)
GLODAP_Cant_obs <- GLODAP_Cant_obs %>%
group_by(lon, lat) %>%
mutate(n = mean(n, na.rm = TRUE)) %>%
ungroup()The mapped Cant product was merged with GLODAP observation by:
- using an identical 1x1° horizontal grid
- linear interpolation of Cant from standard to sampling depth
# GLODAP_Cant_obs <- full_join(GLODAP_Cant_obs, Cant_clim_obs_nr)
GLODAP_Cant_obs <- GLODAP_Cant_obs %>%
filter(n > 1) %>%
group_by(lat, lon) %>%
arrange(depth) %>%
mutate(cant_int = approxfun(depth, cant, rule = 2)(depth)) %>%
ungroup()
# GLODAP_Cant_obs_set <- GLODAP_Cant_obs %>%
# filter(n_cant == 1) %>%
# group_by(lat, lon) %>%
# arrange(depth) %>%
# mutate(cant_int = mean(cant, na.rm = TRUE)) %>%
# ungroup()
ggplot() +
geom_path(
data = GLODAP_Cant_obs %>%
filter(lat == 48.5, lon == 165.5,!is.na(cant)) %>%
arrange(depth),
aes(cant, depth, col = "mapped")
) +
geom_point(
data = GLODAP_Cant_obs %>%
filter(lat == 48.5, lon == 165.5,!is.na(cant)) %>%
arrange(depth),
aes(cant, depth, col = "mapped")
) +
geom_point(
data = GLODAP_Cant_obs %>%
filter(lat == 48.5, lon == 165.5, date == ymd("2018-06-27")),
aes(cant_int, depth, col = "interpolated")
) +
scale_y_reverse() +
scale_color_brewer(palette = "Dark2", name = "") +
labs(title = "Cant interpolation to sampling depth - example profile")
# remove cant data at grid cells without observations
GLODAP <- GLODAP_Cant_obs %>%
filter(!is.na(Cstar)) %>%
mutate(cant = cant_int) %>%
select(-cant_int, n)
rm(GLODAP_Cant_obs)4.1.2 GLODAP + atm. pCO2
GLODAP observations were merged with mean annual atmospheric pCO2 levels by year.
GLODAP <- left_join(GLODAP, co2_atm)4.2 Calculate adjustment
GLODAP <- GLODAP %>%
group_by(era) %>%
mutate(tref = median(year)) %>%
ungroup()
tref <- GLODAP %>%
group_by(era) %>%
summarise(year = median(year)) %>%
ungroup()
co2_atm_tref <- right_join(co2_atm, tref) %>%
select(-year) %>%
rename(pCO2_tref = pCO2)
GLODAP <- full_join(GLODAP, co2_atm_tref)
rm(co2_atm, tref)
GLODAP <- GLODAP %>%
mutate(Cstar_tref_delta =
((pCO2 - pCO2_tref) / (pCO2_tref - 280)) * cant,
Cstar_tref = Cstar - Cstar_tref_delta)4.3 Control plots
4.3.1 Histogram
GLODAP %>%
ggplot(aes(Cstar_tref_delta)) +
geom_histogram()
4.3.2 Time series
GLODAP %>%
sample_n(1e4) %>%
ggplot(aes(year, Cstar_tref_delta, col = cant)) +
geom_point() +
scale_color_viridis_c() +
labs(title = "random subsample 1e4")
5 Selected section plots
A selected section is plotted to demonstrate the magnitude of various parameters and corrections relevant to C*.
GLODAP_cruise <- GLODAP %>%
filter(cruise %in% parameters$cruises_meridional)GLODAP_cruise %>%
arrange(date) %>%
ggplot(aes(lon, lat)) +
geom_raster(data = landmask,
aes(lon, lat), fill = "grey80") +
geom_path() +
geom_point(aes(col = date)) +
coord_quickmap(expand = 0) +
scale_color_viridis_c(trans = "date") +
labs(title = paste("Cruise year:", mean(GLODAP_cruise$year))) +
theme(axis.title = element_blank())
lat_section <-
GLODAP_cruise %>%
ggplot(aes(lat, depth)) +
scale_y_reverse() +
scale_color_viridis_c() +
theme(axis.title.x = element_blank())
lat_section +
geom_point(aes(col = tco2))
lat_section +
geom_point(aes(col = rCP_phosphate))
lat_section +
geom_point(aes(col = talk_05))
lat_section +
geom_point(aes(col = rNP_phosphate_05))
lat_section +
geom_point(aes(col = Cstar))
lat_section +
geom_point(aes(col = -Cstar_tref_delta))
rm(lat_section, GLODAP_cruise)
GLODAP <- GLODAP %>%
select(-c(rCP_phosphate:Cstar, cant:Cstar_tref_delta))6 Isoneutral slabs
The following boundaries for isoneutral slabs were defined:
- Atlantic: -, 26, 26.5, 26.75, 27, 27.25, 27.5, 27.75, 27.85, 27.95, 28.05, 28.1, 28.15, 28.2,
- Indo-Pacific: -, 26, 26.5, 26.75, 27, 27.25, 27.5, 27.75, 27.85, 27.95, 28.05, 28.1,
Continuous neutral densities (gamma) values from GLODAP are grouped into isoneutral slabs.
GLODAP_Atl <- GLODAP %>%
filter(basin == "Atlantic") %>%
mutate(gamma_slab = cut(gamma, parameters$slabs_Atl))
GLODAP_Ind_Pac <- GLODAP %>%
filter(basin == "Indo-Pacific") %>%
mutate(gamma_slab = cut(gamma, parameters$slabs_Ind_Pac))
GLODAP <- bind_rows(GLODAP_Atl, GLODAP_Ind_Pac)
rm(GLODAP_Atl, GLODAP_Ind_Pac)GLODAP_cruise <- GLODAP %>%
filter(cruise %in% parameters$cruises_meridional)
lat_section <-
GLODAP_cruise %>%
ggplot(aes(lat, depth)) +
scale_y_reverse() +
theme(legend.position = "bottom")
lat_section +
geom_point(aes(col = gamma_slab)) +
scale_color_viridis_d()
rm(lat_section, GLODAP_cruise)GLODAP_cruise <- GLODAP %>%
filter(cruise %in% parameters$cruises_meridional)
library(oce)
library(gsw)
# calculate pressure from depth
GLODAP_cruise <- GLODAP_cruise %>%
mutate(CTDPRS = gsw_p_from_z(-depth,
lat))
GLODAP_cruise <- GLODAP_cruise %>%
mutate(THETA = swTheta(salinity = sal,
temperature = tem,
pressure = CTDPRS,
referencePressure = 0,
longitude = lon-180,
latitude = lat))
GLODAP_cruise <- GLODAP_cruise %>%
rename(LATITUDE = lat,
LONGITUDE = lon,
SALNTY = sal,
gamma_provided = gamma)
library(reticulate)
source_python(here::here("code/python_scripts",
"Gamma_GLODAP_python.py"))
GLODAP_cruise <- calculate_gamma(GLODAP_cruise)
GLODAP_cruise <- GLODAP_cruise %>%
mutate(gamma_delta = gamma_provided - GAMMA)
lat_section <-
GLODAP_cruise %>%
ggplot(aes(LATITUDE, CTDPRS)) +
scale_y_reverse() +
theme(legend.position = "bottom")
lat_section +
geom_point(aes(col = gamma_delta)) +
scale_color_viridis_c()
GLODAP_cruise %>%
ggplot(aes(gamma_delta))+
geom_histogram()
rm(lat_section, GLODAP_cruise, cruises_meridional)7 Observations coverage
GLODAP <- GLODAP %>%
mutate(era = factor(era, c("JGOFS_WOCE", "GO_SHIP", "new_era"))) %>%
mutate(gamma_slab = factor(gamma_slab),
gamma_slab = factor(gamma_slab, levels = rev(levels(gamma_slab))))
GLODAP %>%
filter(basin == "Atlantic") %>%
ggplot(aes(lat, gamma_slab)) +
geom_bin2d(binwidth = 5) +
scale_fill_viridis_c(option = "magma", direction = -1, trans = "log10") +
scale_x_continuous(breaks = seq(-100,100,20)) +
facet_grid(era~basin)
GLODAP %>%
filter(basin == "Indo-Pacific") %>%
ggplot(aes(lat, gamma_slab)) +
geom_bin2d(binwidth = 5) +
scale_fill_viridis_c(option = "magma", direction = -1, trans = "log10") +
scale_x_continuous(breaks = seq(-100,100,20)) +
facet_grid(era~basin)
8 Individual cruise sections
Zonal and meridional section plots are produce for each cruise individually and can be downloaded here.
cruises <- GLODAP %>%
group_by(cruise) %>%
summarise(date_mean = mean(date, na.rm = TRUE),
n = n()) %>%
ungroup() %>%
arrange(date_mean)
GLODAP <- full_join(GLODAP, cruises)
n <- 0
for (i_cruise in unique(cruises$cruise)) {
#i_cruise <- unique(cruises$cruise)[1]
n <- n+1
print(n)
GLODAP_cruise <- GLODAP %>%
filter(cruise == i_cruise) %>%
arrange(date)
cruises_cruise <- cruises %>%
filter(cruise == i_cruise)
map <- GLODAP_cruise %>%
ggplot(aes(lon, lat)) +
geom_raster(data = landmask,
aes(lon, lat), fill = "grey80") +
geom_point(aes(col=date)) +
coord_quickmap(expand = FALSE) +
scale_color_viridis_c(trans = "date") +
labs(title = paste("Mean date:", cruises_cruise$date_mean,
"| cruise:", cruises_cruise$cruise,
"| n(samples):", cruises_cruise$n))
lon_section <- GLODAP_cruise %>%
ggplot(aes(lon, depth)) +
scale_y_reverse() +
scale_color_viridis_c()
lon_tco2 <- lon_section+
geom_point(aes(col=tco2))
lon_talk <- lon_section+
geom_point(aes(col=talk))
lon_phosphate <- lon_section+
geom_point(aes(col=phosphate))
lon_oxygen <- lon_section+
geom_point(aes(col=oxygen))
lon_aou <- lon_section+
geom_point(aes(col=aou))
lon_phosphate_star <- lon_section+
geom_point(aes(col=phosphate_star))
lon_nitrate <- lon_section+
geom_point(aes(col=nitrate))
lon_Cstar <- lon_section+
geom_point(aes(col=Cstar))
lat_section <- GLODAP_cruise %>%
ggplot(aes(lat, depth)) +
scale_y_reverse() +
scale_color_viridis_c()
lat_tco2 <- lat_section+
geom_point(aes(col=tco2))
lat_talk <- lat_section+
geom_point(aes(col=talk))
lat_phosphate <- lat_section+
geom_point(aes(col=phosphate))
lat_oxygen <- lat_section+
geom_point(aes(col=oxygen))
lat_aou <- lat_section+
geom_point(aes(col=aou))
lat_phosphate_star <- lat_section+
geom_point(aes(col=phosphate_star))
lat_nitrate <- lat_section+
geom_point(aes(col=nitrate))
lat_Cstar <- lat_section+
geom_point(aes(col=Cstar))
hist_tco2 <- GLODAP_cruise %>%
ggplot(aes(tco2)) +
geom_histogram()
hist_talk <- GLODAP_cruise %>%
ggplot(aes(talk)) +
geom_histogram()
hist_phosphate <- GLODAP_cruise %>%
ggplot(aes(phosphate)) +
geom_histogram()
hist_oxygen <- GLODAP_cruise %>%
ggplot(aes(oxygen)) +
geom_histogram()
hist_aou <- GLODAP_cruise %>%
ggplot(aes(aou)) +
geom_histogram()
hist_phosphate_star <- GLODAP_cruise %>%
ggplot(aes(phosphate_star)) +
geom_histogram()
hist_nitrate <- GLODAP_cruise %>%
ggplot(aes(nitrate)) +
geom_histogram()
hist_Cstar <- GLODAP_cruise %>%
ggplot(aes(Cstar)) +
geom_histogram()
(map /
((hist_tco2 / hist_talk / hist_phosphate / hist_Cstar) |
(hist_oxygen / hist_phosphate_star / hist_nitrate / hist_aou)
)) |
((lat_tco2 / lat_talk / lat_phosphate / lat_oxygen / lat_aou / lat_phosphate_star / lat_nitrate / lat_Cstar) |
(lon_tco2 / lon_talk / lon_phosphate / lon_oxygen / lon_aou /lon_phosphate_star / lon_nitrate / lon_Cstar))
ggsave(here::here("output/figure/eMLR/data_preparation/all_cruises_clean",
paste("GLODAP_cruise_date",
cruises_cruise$date_mean,
"n",
cruises_cruise$n,
"cruise",
cruises_cruise$cruise,
".png",
sep = "_")),
width = 20, height = 12)
rm(map,
lon_section, lat_section,
lat_tco2, lat_talk, lat_phosphate, lon_tco2, lon_talk, lon_phosphate,
GLODAP_cruise, cruises_cruise)
}9 Write files
GLODAP <- GLODAP %>%
rename(Cstar = Cstar_tref)
GLODAP %>% write_csv(here::here("data/GLODAPv2_2020/_summarized_data_files",
"GLODAP_MLR_fitting_ready.csv"))
co2_atm_tref %>%
write_csv(here::here(
"data/pCO2_atmosphere/_summarized_data_files",
"co2_atm_tref.csv"
))
sessionInfo()R version 4.0.2 (2020-06-22)
Platform: x86_64-w64-mingw32/x64 (64-bit)
Running under: Windows 10 x64 (build 18363)
Matrix products: default
locale:
[1] LC_COLLATE=English_Germany.1252 LC_CTYPE=English_Germany.1252
[3] LC_MONETARY=English_Germany.1252 LC_NUMERIC=C
[5] LC_TIME=English_Germany.1252
attached base packages:
[1] stats graphics grDevices utils datasets methods base
other attached packages:
[1] marelac_2.1.10 shape_1.4.4 patchwork_1.0.1 lubridate_1.7.9
[5] forcats_0.5.0 stringr_1.4.0 dplyr_1.0.0 purrr_0.3.4
[9] readr_1.3.1 tidyr_1.1.0 tibble_3.0.3 ggplot2_3.3.2
[13] tidyverse_1.3.0 workflowr_1.6.2
loaded via a namespace (and not attached):
[1] Rcpp_1.0.5 here_0.1 assertthat_0.2.1 rprojroot_1.3-2
[5] digest_0.6.25 R6_2.4.1 cellranger_1.1.0 backports_1.1.8
[9] reprex_0.3.0 evaluate_0.14 httr_1.4.2 pillar_1.4.6
[13] rlang_0.4.7 readxl_1.3.1 rstudioapi_0.11 whisker_0.4
[17] blob_1.2.1 rmarkdown_2.3 labeling_0.3 munsell_0.5.0
[21] broom_0.7.0 compiler_4.0.2 httpuv_1.5.4 modelr_0.1.8
[25] xfun_0.16 pkgconfig_2.0.3 htmltools_0.5.0 tidyselect_1.1.0
[29] viridisLite_0.3.0 fansi_0.4.1 crayon_1.3.4 dbplyr_1.4.4
[33] withr_2.2.0 later_1.1.0.1 gsw_1.0-5 grid_4.0.2
[37] jsonlite_1.7.0 gtable_0.3.0 lifecycle_0.2.0 DBI_1.1.0
[41] git2r_0.27.1 magrittr_1.5 seacarb_3.2.13 scales_1.1.1
[45] cli_2.0.2 stringi_1.4.6 oce_1.2-0 farver_2.0.3
[49] fs_1.4.2 promises_1.1.1 testthat_2.3.2 xml2_1.3.2
[53] ellipsis_0.3.1 generics_0.0.2 vctrs_0.3.2 RColorBrewer_1.1-2
[57] tools_4.0.2 glue_1.4.1 hms_0.5.3 yaml_2.2.1
[61] colorspace_1.4-1 rvest_0.3.6 knitr_1.30 haven_2.3.1