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Task

Explore BGC-Argo pH data through timeseries and monthly climatological maps

path_argo <- '/nfs/kryo/work/updata/bgc_argo_r_argodata'
path_emlr_utilities <- "/nfs/kryo/work/jenmueller/emlr_cant/utilities/files/"
path_basin_mask <- "/nfs/kryo/work/updata/reccap2/"

Load pH data

Load in delayed-mode adjusted pH data from the data files created in Loading Data

# keep only pH data and associated CTD variables 
path_argo_preprocessed <- paste0(path_argo, "/preprocessed_bgc_data")

# load in surface pH data 
ph_surface_2x2 <- read_rds(file = paste0(path_argo_preprocessed, '/ph_surface_2x2.rds'))

ph_surface_1x1 <- read_rds(file = paste0(path_argo_preprocessed, "/ph_surface_1x1.rds"))

region_masks_all_seamask_2x2 <- read_rds(file = paste0(
  path_argo_preprocessed, "/region_masks_all_seamask_2x2.rds"))

region_masks_all_2x2 <- read_rds(file = paste0(path_argo_preprocessed, "/region_masks_all_2x2.rds"))

Southern Ocean surface pH

The focus here is on surface pH (in the top 20 m of the watercolumn), in the region south of 30ºS

# select pH data for the Southern Ocean, as defined by the RECCAP regions  
ph_surface_SO <- ph_surface_2x2 %>%
  filter(region == 'southern', 
         value != 0)

# check the correct latitudes, QC flags, and depth levels have been filtered
#max(ph_surface_SO$lat)
#min(ph_surface_SO$lat)
# table(ph_surface_SO$ph_in_situ_total_adjusted_qc)
# max(ph_surface_SO$depth)
# min(ph_surface_SO$date)
# max(ph_surface_SO$date)

Data offset with depth

Plot the difference between in-situ observed pH and the profile-mean surface pH for the upper 20 m. This difference represents the variability of the surface pH values with respect to the mean surface pH of the upper 20 m.

# calculate the mean pH for each surface profile 
mean_profile_ph <- ph_surface_SO %>% 
  group_by(float_serial_no, cycle_number) %>% 
  mutate(mean_prof_ph = mean(ph_in_situ_total_adjusted, na.rm = TRUE), 
         .before = depth) %>% 
  ungroup() %>% 
  mutate(offset = ph_in_situ_total_adjusted-mean_prof_ph,   
         .after = mean_prof_ph) # subtract the mean profile pH from the measured in situ pH

mean_profile_ph %>%
  ggplot()+
  geom_point(aes(x = offset, y = depth, col = as.character(year)), size = 0.3, pch = 19) +
  scale_y_reverse()+
  geom_vline(xintercept = 0, col = 'red', size = 0.6)+
  labs(x = 'offset (pH units)',
       y = 'depth (m)',
       col = 'year',
       title = 'in situ pH - mean profile pH')

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Bin the pH data into 2m-depth intervals and calculate the offset for each pH observation in each depth interval relative to the profile-mean pH

# bin the ph values into 2m bins and calculate the offset for each 2m bin 
mean_profile_ph_binned <- ph_surface_SO %>% 
  mutate(depth = cut(depth, seq(0, 20, 2), seq(1, 19, 2)),
         depth = as.numeric(as.character(depth))) %>% 
  group_by(float_serial_no, cycle_number) %>% 
  mutate(mean_prof_ph = mean(ph_in_situ_total_adjusted, na.rm = TRUE),
         .before = depth) %>% 
  ungroup() %>% 
  mutate(offset = ph_in_situ_total_adjusted-mean_prof_ph, 
         .after = mean_prof_ph)

# plot the offset of the depth-binned values 
mean_profile_ph_binned %>%
  ggplot()+
  geom_point(aes(x = offset, y = depth, col = as.character(year)), size = 0.3, pch = 19) +
  scale_y_reverse()+
  geom_vline(xintercept = 0, col = 'red', size = 0.6)+
  labs(x = 'offset (pH units)',
       y = 'depth (m)',
       col = 'year',
       title = 'in situ pH - mean profile pH (2m depth bins)')

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Monthly climatological map

Create a climatological monthly map of surface pH, in a 2x2º longitude/latitude grid, for the region south of 30ºS (monthly pH averaged over April 2014-August 2021)

# average pH values in the top 20 m for each month in each 2 x 2º longitude/latitude grid 
ph_clim_SO <- ph_surface_SO %>%
  group_by(lat, lon, month) %>%
  summarise(ph_clim_month = mean(ph_in_situ_total_adjusted))
`summarise()` has grouped output by 'lat', 'lon'. You can override using the `.groups` argument.
# read in the map from updata
map <-
  read_rds(paste(path_emlr_utilities,
                 "map_landmask_WOA18.rds",
                 sep = ""))

# map a monthly climatology of pH (April 2014 - August 2021)
map +
  geom_tile(data = ph_clim_SO,
            aes(lon, lat, fill = ph_clim_month)) +
  lims(y = c(-85, -25)) +
  scale_fill_viridis_c() +
  labs(x = 'lon',
       y = 'lat',
       fill = 'pH',
       title = 'Monthly climatological \nArgo pH (Apr 2014 - Aug 2021)') +
  theme(legend.position = 'right') +
  facet_wrap(~month, ncol = 2)
Warning: Raster pixels are placed at uneven vertical intervals and will be
shifted. Consider using geom_tile() instead.
Warning: Removed 153708 rows containing missing values (geom_raster).

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basemap(limits = -32, data = ph_clim_SO) +   # change to polar projection 
  geom_spatial_tile(data = ph_clim_SO, 
            aes(x = lon,
                y = lat,
                fill = ph_clim_month),
            linejoin = 'mitre',
            col = 'transparent',
            detail = 60)+
  scale_fill_viridis_c()+
  theme(legend.position = 'bottom')+
  labs(x = 'lon',
       y = 'lat',
       fill = 'pH',
       title = 'monthly climatological \nArgo pH (Apr 2014 - Aug 2021)')+
  facet_wrap(~month)
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()
Assuming `crs = 4326` in stat_spatial_rect()

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Monthly timeseries

Timeseries of monthly mean pH values, over the three different Southern Ocean regions (separated based on RECCAP biomes):

# plot the region separations on a map 
ggplot() +
  geom_raster(data = region_masks_all_seamask_2x2 %>% 
                filter(seamask == 0), 
              aes(x = lon, y = lat)) +
  geom_raster(data = region_masks_all_2x2 %>% 
                filter(region == 'southern',
                       value != 0), 
              aes(x = lon, 
                  y = lat, 
                  fill = value)) +
  coord_quickmap(expand = 0) +
  labs(title = 'Southern Ocean RECCAP regions', 
       fill = 'region')
Warning: Raster pixels are placed at uneven vertical intervals and will be
shifted. Consider using geom_tile() instead.

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# plot a timeseries of monthly values over the whole southern ocean south of 30ºS
ph_month_SO <- ph_surface_SO %>%
  group_by(year, month, value) %>%
  summarise(ph_ave = mean(ph_in_situ_total_adjusted))
`summarise()` has grouped output by 'year', 'month'. You can override using the `.groups` argument.
# timeseries of monthly pH values over 2014-2021 (separate panels for each month)
ph_month_SO %>%
  ggplot(aes(x = year, 
             y = ph_ave, 
             group = value, 
             col = value)) +
  facet_wrap(~month) +
  geom_line() +
  geom_point() +
  labs(x = 'year', 
       y = 'pH in situ (total scale)', 
       title = 'monthly mean Argo pH (Apr 2014-Aug 2021, Southern Ocean)', 
       col = 'region')

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#all months on one plot in different colors (not very nice plot)
# ph_month_SO %>%
#   ggplot(aes(x = year, y = ph_ave, group = month, col = as.character(month))) +
#   geom_line() +
#   geom_point() +
#   labs(x = 'year', y = 'pH in situ (total scale)', title = 'monthly mean pH (Apr 2014-Aug 2021)')

Plot the monthly average pH, per year (from Jan 2015 - Dec 2020), for each Southern Ocean RECCAP region (1, 2, 3)

# timeseries of monthly pH values for each year (separate years on the same plot)
ph_month_SO %>%
  filter(year != 2014,
         year != 2021,
         value != 0) %>%    # remove the two years that are missing data (keep only data for full years)
  ggplot(aes(x = month, 
             y = ph_ave, 
             group = year,
             col = as.character(year)))+
  geom_line()+
  geom_point()+
  scale_x_continuous(breaks = seq(1, 12, 2))+
  facet_wrap(~value)+
  labs(x = 'month',
       y = 'pH in situ (total scale)',
       title = 'monthly mean Argo pH (Jan 2015-Dec 2020, Southern Ocean)',
       col = 'year')

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# calculate a yearly average ph (one ph value per year, for the whole domain)
ph_year_SO <- ph_surface_SO %>%
  group_by(year, value) %>%
  summarise(ph_ave = mean(ph_in_situ_total_adjusted))

# plot a timeseries of the yearly average pH value (one value per year)
ph_year_SO %>%
  ggplot(aes(x = year, y = ph_ave, group = value, col = value))+
  geom_line()+
  geom_point()+
  labs(x = 'year',
       y = 'pH in situ (total scale)',
       title = 'yearly mean Argo pH (Apr 2014-Aug 2021, south of 30ºS)', 
       col = 'region')

Northeast Pacific surface pH

Focus on surface pH in the northeast Pacific Ocean (10ºN - 70ºN, -190ºE - -140ºE)

# select only best pH data (with QC flag 1) between 10 and 70ºN, and 190 and 140ºW, for the top 20 m of the watercolumn
ph_nepacific <- ph_surface_2x2 %>%
  mutate(depth = swDepth(pres_adjusted, latitude = lat), .before = pres_adjusted) %>%
  filter(ph_in_situ_total_adjusted_qc == '1',   # keep only 'good' data
        between(lat, 10, 70),
        between(lon, 190, 240),               # NE Pacific 
        depth <= 20) %>%              # keep only data above or at 20 m depth
  mutate(
    year = year(date),     # separate the year and month from the date column
    month = month(date), .after = n_prof
  )
# longitudes larger than -180ºE are lon-380

Monthly climatological map

Create a map of climatological monthly surface pH values, in the north-west Pacific ocean (10ºN - 70ºN, -190ºE, -140ºE), for

# average pH values in the top 20 m for each month in each 2 x 2º longitude/latitude grid 
ph_mean_nepacific <- ph_nepacific %>%
  group_by(lat, lon, month) %>%
  summarise(ph_ave_month = mean(ph_in_situ_total_adjusted))
`summarise()` has grouped output by 'lat', 'lon'. You can override using the `.groups` argument.
# map a monthly climatology of surface pH (Jan 2013 - August 2021)
map +
  geom_tile(data = ph_mean_nepacific,
            aes(lon, lat, fill = ph_ave_month)) +
  lims(y = c(5, 60), 
       x = c(180, 250)) +
  scale_fill_viridis_c() +
  labs(x = 'lon',
       y = 'lat',
       fill = 'pH',
       title = 'Monthly average pH (Jan 2013-Aug 2021)') +
  theme(legend.position = 'right')+
  facet_wrap(~month)
Warning: Removed 219516 rows containing missing values (geom_raster).

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# using the ggOceanMaps package
basemap(limits = c(-180, -110, 7, 60), data = ph_mean_nepacific) +
  geom_spatial_tile(data = ph_mean_nepacific, 
              aes(x = lon,
                  y = lat, 
                  fill = ph_ave_month))+
  scale_fill_viridis_c()+
  facet_wrap(~month) + 
  labs(x = 'lon', 
       y = 'lat',
       fill = 'pH',
       title = 'Monthly average pH (Jan 2013-Aug 2021)')
# haven't figured out why the data isn't being plotted 

Monthly timeseries

Timeseries of monthly mean pH, averaged over the whole NE-Pacific region (10ºN - 70ºN, -190ºE - -140ºE), in the upper 20 m of the watercolumn.

# plot a timeseries of monthly values over the whole southern ocean south of 30ºS
ph_month_nepacific <- ph_nepacific %>%
  group_by(year, month) %>%
  summarise(ph_ave = mean(ph_in_situ_total_adjusted))
`summarise()` has grouped output by 'year'. You can override using the `.groups` argument.
# timeseries of monthly pH values over 2014-2021 (separate panels for each month)
ph_month_nepacific %>%
  ggplot(aes(x = year, y = ph_ave)) +
  facet_wrap(~month) +
  scale_x_continuous(breaks = seq(2013, 2021, 2)) +
  geom_line() +
  geom_point() +
  labs(x = 'year', 
       y = 'pH in situ (total scale)', 
       title = 'monthly mean pH (Jan 2013-Aug 2021, NE Pacific)')

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Monthly average pH, per year, over the NE Pacific region

# timeseries of monthly pH values for each year (separate years on the same plot)
ph_month_nepacific %>%
  filter(year != 2016,
         year != 2021) %>%    # remove the two years that are missing data (keep only data for full years)
  ggplot(aes(x = month, y = ph_ave, group = year, col = as.character(year)))+
  geom_line()+
  geom_point()+
  scale_x_continuous(breaks = seq(1, 12, 1))+
  labs(x = 'month',
       y = 'pH in situ (total scale)',
       title = 'monthly mean pH (Jan 2013-Dec 2020, NE Pacific)',
       col = 'year')

Version Author Date
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sessionInfo()
R version 4.0.3 (2020-10-10)
Platform: x86_64-pc-linux-gnu (64-bit)
Running under: openSUSE Leap 15.2

Matrix products: default
BLAS:   /usr/local/R-4.0.3/lib64/R/lib/libRblas.so
LAPACK: /usr/local/R-4.0.3/lib64/R/lib/libRlapack.so

locale:
 [1] LC_CTYPE=en_US.UTF-8       LC_NUMERIC=C              
 [3] LC_TIME=en_US.UTF-8        LC_COLLATE=en_US.UTF-8    
 [5] LC_MONETARY=en_US.UTF-8    LC_MESSAGES=en_US.UTF-8   
 [7] LC_PAPER=en_US.UTF-8       LC_NAME=C                 
 [9] LC_ADDRESS=C               LC_TELEPHONE=C            
[11] LC_MEASUREMENT=en_US.UTF-8 LC_IDENTIFICATION=C       

attached base packages:
[1] stats     graphics  grDevices utils     datasets  methods   base     

other attached packages:
 [1] ggOceanMaps_0.4.3   ggspatial_1.1.5     oce_1.4-0          
 [4] testthat_3.0.4      sf_1.0-2            gsw_1.0-6          
 [7] lubridate_1.7.9     argodata_0.0.0.9000 forcats_0.5.0      
[10] stringr_1.4.0       dplyr_1.0.5         purrr_0.3.4        
[13] readr_1.4.0         tidyr_1.1.3         tibble_3.1.3       
[16] ggplot2_3.3.5       tidyverse_1.3.0     workflowr_1.6.2    

loaded via a namespace (and not attached):
 [1] smoothr_0.1.2         fs_1.5.0              httr_1.4.2           
 [4] rprojroot_2.0.2       tools_4.0.3           backports_1.1.10     
 [7] bslib_0.2.5.1         utf8_1.2.2            rgdal_1.5-18         
[10] R6_2.5.1              KernSmooth_2.23-17    rgeos_0.5-5          
[13] DBI_1.1.1             colorspace_2.0-2      raster_3.4-5         
[16] withr_2.4.2           sp_1.4-4              tidyselect_1.1.0     
[19] compiler_4.0.3        git2r_0.27.1          cli_3.0.1            
[22] rvest_0.3.6           RNetCDF_2.4-2         xml2_1.3.2           
[25] labeling_0.4.2        sass_0.4.0            scales_1.1.1         
[28] classInt_0.4-3        ggOceanMapsData_1.0.1 proxy_0.4-26         
[31] digest_0.6.27         rmarkdown_2.10        pkgconfig_2.0.3      
[34] htmltools_0.5.1.1     highr_0.8             dbplyr_1.4.4         
[37] rlang_0.4.11          readxl_1.3.1          rstudioapi_0.13      
[40] farver_2.1.0          jquerylib_0.1.4       generics_0.1.0       
[43] jsonlite_1.7.2        magrittr_2.0.1        Rcpp_1.0.7           
[46] munsell_0.5.0         fansi_0.5.0           abind_1.4-5          
[49] lifecycle_1.0.0       stringi_1.5.3         whisker_0.4          
[52] yaml_2.2.1            grid_4.0.3            blob_1.2.1           
[55] parallel_4.0.3        promises_1.2.0.1      crayon_1.4.1         
[58] lattice_0.20-41       stars_0.5-2           haven_2.3.1          
[61] hms_0.5.3             knitr_1.33            pillar_1.6.2         
[64] codetools_0.2-16      reprex_0.3.0          glue_1.4.2           
[67] evaluate_0.14         modelr_0.1.8          vctrs_0.3.8          
[70] httpuv_1.6.2          cellranger_1.1.0      gtable_0.3.0         
[73] assertthat_0.2.1      xfun_0.25             lwgeom_0.2-5         
[76] broom_0.7.9           e1071_1.7-8           later_1.3.0          
[79] viridisLite_0.4.0     class_7.3-17          units_0.7-2          
[82] ellipsis_0.3.2