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1 Required data

Required are:

  • Synthetic cmorized model subsetting data based on preprocessed GLODAP data
    • cleaned data file
  • Cmorized annual cant field for three reference year
  • Cmorized annual mean atmospheric pCO2
if (params_local$subsetting == "GLODAP") {
  
GLODAP <-
  read_csv(paste(
    path_version_data,
    "GLODAPv2.2020_clean_GLODAP.csv",
    sep = ""
  ))

}

if (params_local$subsetting == "random") {
  
GLODAP <-
  read_csv(paste(
    path_version_data,
    "GLODAPv2.2020_clean_random.csv",
    sep = ""
  ))

}

2 Calculation of tref

Calculate the reference year for each era and store it as csv file for further selection of corresponding Cant fields.

# calculate reference year
tref <- GLODAP %>%
  group_by(era) %>%
  summarise(year = round(median(year))) %>%
  ungroup()

# write file
tref  %>%  write_csv(paste(path_version_data,
                           "tref.csv",
                           sep = ""))
cant_tref_1 <-
  read_csv(paste(
    path_preprocessing,
    "cant_annual_field_", params_local$model_runs, "/cant_",
    unique(tref$year[1]),
    ".csv",
    sep = ""
  ))

cant_tref_2 <-
  read_csv(paste(
    path_preprocessing,
    "cant_annual_field_", params_local$model_runs, "/cant_",
    unique(tref$year[2]),
    ".csv",
    sep = ""
  ))

cant_tref_3 <-
  read_csv(paste(
    path_preprocessing,
    "cant_annual_field_", params_local$model_runs, "/cant_",
    unique(tref$year[3]),
    ".csv",
    sep = ""
  ))

co2_atm <-
  read_csv(paste(path_preprocessing,
                 "co2_atm.csv",
                 sep = ""))

3 PO4*

3.1 Calculation

The predictor PO4* was be calculated according to Clement and Gruber (2018), ie based on oxygen. Please note that an erroneous equations for PO4* calculation is given in the supplement of Gruber et al (2019), based on nitrate.

Here we use following equation:

print(b_phosphate_star)
function (phosphate, oxygen) 
{
    phosphate_star = phosphate + (oxygen/params_local$rPO) - 
        params_local$rPO_offset
    return(phosphate_star)
}
if ("phosphate_star" %in% params_local$MLR_predictors) {
GLODAP <- GLODAP %>% 
  mutate(phosphate_star = b_phosphate_star(phosphate, oxygen))
}

4 C*

C* serves as a conservative tracer of anthropogenic CO2 uptake. It is derived from synthetic subsetted DIC by removing the impact of

  • organic matter formation and respiration
  • calcification and calcium carbonate dissolution

Contributions of those processes are estimated from phosphate and alkalinity concentrations.

4.1 Stoichiometric ratios

The stoichiometric nutrient ratios for the production and mineralization of organic matter were set to:

  • C/P: 117
  • N/P: 16

4.2 Calculation

C* was calculated as:

print(b_cstar)
function (tco2, phosphate, talk) 
{
    cstar = tco2 - (params_local$rCP * phosphate) - 0.5 * (talk - 
        (params_local$rNP * phosphate))
    return(cstar)
}
GLODAP <- GLODAP %>% 
  mutate(rCP_phosphate = -params_local$rCP * phosphate,
         talk_05 = -0.5 * talk,
         rNP_phosphate_05 = -0.5 * params_local$rNP * phosphate,
         cstar = b_cstar(tco2, phosphate, talk))

4.3 Reference year adjustment

To adjust C* values to the reference year of each observation period, we assume a transient steady state change of cant between the time of model subsetting and the reference year. The adjustment requires an approximation of the cant concentration at the reference year. We here use the model-estimated annual cant field for each reference year.

4.3.1 Cant at tref

Read in Cant field for each reference year.

# print reference year table
kable(tref) %>%
  add_header_above() %>%
  kable_styling()
era year
1982-1999 1995
2000-2012 2007
2013-2019 2016
# join cant with tref
cant_3d <- bind_rows(cant_tref_1, cant_tref_2, cant_tref_3)

cant_3d <- left_join(cant_3d, tref) %>%
  arrange(lon, lat, depth) %>% 
  select(lon, lat, depth, era, cant_total)

rm(cant_tref_1, cant_tref_2, cant_tref_3)
map +
  geom_raster(data = cant_3d %>% filter(depth == 5),
              aes(lon, lat, fill = cant_total)) +
  facet_wrap(~ era, ncol = 1) +
  scale_fill_viridis_c() +
  labs(title = "Surface total Cant concentration")

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d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
fa85b93 jens-daniel-mueller 2021-01-06

4.3.2 Combine GLODAP + Cant

# observations grid per era
GLODAP_obs_grid_era <- GLODAP %>% 
  distinct(lat, lon, era)

# cant data at observations grid
cant_3d_obs <- left_join(
  GLODAP_obs_grid_era,
  cant_3d)

# calculate number of cant data points per grid cell
cant_3d_obs <- cant_3d_obs %>%
  group_by(lon, lat, era) %>% 
  mutate(n = n()) %>% 
  ungroup()

# GLODAP-based model subset with only one Cant value
map +
  geom_bin2d(data = cant_3d_obs,
             aes(lon, lat),
             binwidth = 1) +
  scale_fill_viridis_c() +
  facet_wrap(~ era, ncol = 1) +
  labs(title = "Number of Cant depth levels",
       subtitle = "available per latxlon grid cell")

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ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
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24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
fa85b93 jens-daniel-mueller 2021-01-06
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
rm(cant_3d, GLODAP_obs_grid_era)

GLODAP_cant_obs <- full_join(GLODAP, cant_3d_obs)

rm(GLODAP, cant_3d_obs)

# fill number of cant data points per grid cell to all model subsetting
GLODAP_cant_obs <- GLODAP_cant_obs %>%
  group_by(lon, lat, era) %>% 
  fill(n, .direction = "updown") %>% 
  ungroup()

The model-estimated annual cant fields were merged with GLODAP-based synthetic cmorized model subsetting by:

  • using an identical 1x1° horizontal grid
  • linear interpolation of Cant from standard to subsetting depth
# define positive cant values
GLODAP_cant_obs <- GLODAP_cant_obs %>%
  mutate(cant_total_pos = if_else(cant_total < 0, 0, cant_total))

# interpolate cant to subsetting depth
GLODAP_cant_obs_int <- GLODAP_cant_obs %>%
  filter(n > 1) %>% 
  group_by(lat, lon, era) %>%
  arrange(depth) %>%
  mutate(cant_int = approxfun(depth, cant_total_pos, rule = 2)(depth)) %>%
  ungroup()

# set cant for subsetting depth if only one cant available
#GLODAP_cant_obs_set <- GLODAP_cant_obs %>%
#  filter(n == 1) %>%
#  group_by(lat, lon, era) %>%
#  mutate(cant_int = mean(cant_total, na.rm = TRUE)) %>%
#  ungroup()

### bin data sets with interpolated and set cant
GLODAP_cant_obs <- GLODAP_cant_obs_int
rm(GLODAP_cant_obs_int)

if (params_local$subsetting == "GLODAP") {
  ggplot() +
    geom_path(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, !is.na(cant_total)) %>%
        arrange(depth),
      aes(cant_total, depth, col = "mapped")
    ) +
    geom_point(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, !is.na(cant_total)) %>%
        arrange(depth),
      aes(cant_total, depth, col = "mapped")
    ) +
    geom_point(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, date == ymd("2018-06-27")),
      aes(cant_int, depth, col = "interpolated")
    ) +
    scale_y_reverse() +
    facet_wrap( ~ era) +
    scale_color_brewer(palette = "Dark2", name = "") +
    labs(title = "Cant interpolation to subsetting depth - example profile")
  
}

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
7cdea0c jens-daniel-mueller 2021-01-06
fa85b93 jens-daniel-mueller 2021-01-06
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
fb8a752 Donghe-Zhu 2020-12-23
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
if (params_local$subsetting == "random") {
  ggplot() +
    geom_path(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, !is.na(cant_total)) %>%
        arrange(depth),
      aes(cant_total, depth, col = "mapped")
    ) +
    geom_point(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, !is.na(cant_total)) %>%
        arrange(depth),
      aes(cant_total, depth, col = "mapped")
    ) +
    geom_point(
      data = GLODAP_cant_obs %>%
        filter(lat == 48.5, lon == 165.5, month == 6),
      aes(cant_int, depth, col = "interpolated")
    ) +
    scale_y_reverse() +
    facet_wrap( ~ era) +
    scale_color_brewer(palette = "Dark2", name = "") +
    labs(title = "Cant interpolation to subsetting depth - example profile")
  
}

# remove cant data at grid cells without observations
GLODAP <- GLODAP_cant_obs %>%
  filter(!is.na(cstar)) %>%
  mutate(cant_total_pos = cant_int) %>%
  select(-c(cant_int, cant_total, n))

rm(GLODAP_cant_obs)

4.3.3 Merge GLODAP + atm. pCO2

GLODAP-based subsetting were merged with mean annual atmospheric pCO2 levels by year.

GLODAP <- left_join(GLODAP, co2_atm)

4.3.4 Calculation

# assign reference year
GLODAP <- GLODAP %>% 
  group_by(era) %>% 
  mutate(tref = median(year)) %>% 
  ungroup()

# extract atm pCO2 at reference year
co2_atm_tref <- right_join(co2_atm, tref) %>% 
  select(-year) %>% 
  rename(pCO2_tref = pCO2)

# merge atm pCO2 at tref with GLODAP
GLODAP <- full_join(GLODAP, co2_atm_tref)
rm(co2_atm, tref)

# calculate cstar for reference year
GLODAP <- GLODAP %>%
  mutate(
    cstar_tref_delta =
      ((pCO2 - pCO2_tref) / (pCO2_tref - params_local$preind_atm_pCO2)) * cant_total_pos,
    cstar_tref = cstar - cstar_tref_delta)

4.4 Control plots

GLODAP %>% 
  ggplot(aes(cstar_tref_delta)) +
  geom_histogram(binwidth = 1) +
  labs(title = "Histogramm with binwidth = 1")

Version Author Date
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ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
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24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
7cdea0c jens-daniel-mueller 2021-01-06
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
fb8a752 Donghe-Zhu 2020-12-23
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
GLODAP %>% 
  sample_n(1e4) %>% 
  ggplot(aes(year, cstar_tref_delta, col = cant_total_pos)) +
  geom_point() +
  scale_color_viridis_c() +
  labs(title = "Time series of random subsample 1e4")

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
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b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
a076226 Donghe-Zhu 2021-01-11
7cdea0c jens-daniel-mueller 2021-01-06
fa85b93 jens-daniel-mueller 2021-01-06
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a499f10 Donghe-Zhu 2021-01-05
fb8a752 Donghe-Zhu 2020-12-23
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
GLODAP %>% 
  ggplot(aes(year, cstar_tref_delta)) +
  geom_bin2d(binwidth = 1) +
  scale_fill_viridis_c(trans = "log10") +
  labs(title = "Heatmap with binwidth = 1")

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
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5 Selected section plots

A selected section is plotted to demonstrate the magnitude of various parameters and corrections relevant to C*.

if (params_local$subsetting == "GLODAP") {

GLODAP_cruise <- GLODAP %>% 
  filter(cruise %in% params_global$cruises_meridional)

}

if (params_local$subsetting == "random") {
  
  GLODAP_cruise <- GLODAP %>%
    filter(lon %in% params_global$lon_Atl_section)
  
}
if (params_local$subsetting == "GLODAP") {
  map +
    geom_path(data = GLODAP_cruise %>%
                arrange(date),
              aes(lon, lat)) +
    geom_point(data = GLODAP_cruise %>%
                 arrange(date),
               aes(lon, lat, col = date)) +
    scale_color_viridis_c(trans = "date") +
    labs(title = paste("Cruise year:", mean(GLODAP_cruise$year)))
}

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
c8b76b3 jens-daniel-mueller 2020-12-19
if (params_local$subsetting == "random") {
  map +
    geom_path(data = GLODAP_cruise,
              aes(lon, lat)) +
    geom_point(data = GLODAP_cruise,
               aes(lon, lat)) +
    scale_color_viridis_c(trans = "date") +
    labs(title = paste("Cruise year:", mean(GLODAP_cruise$year)))
  
}

lat_section <-
  GLODAP_cruise %>%
  ggplot(aes(lat, depth)) +
  scale_y_reverse() +
  scale_fill_viridis_c() +
  theme(axis.title.x = element_blank())

for (i_var in c("tco2",
                "rCP_phosphate",
                "talk_05",
                "rNP_phosphate_05",
                "cstar",
                "cstar_tref")) {
  print(lat_section +
          stat_summary_2d(aes(z = !!sym(i_var))) +
          scale_fill_viridis_c(name = i_var)
        )
  
}

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
e5cb81a Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
7cdea0c jens-daniel-mueller 2021-01-06
fa85b93 jens-daniel-mueller 2021-01-06
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
fb8a752 Donghe-Zhu 2020-12-23
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
rm(lat_section, GLODAP_cruise)

6 Isoneutral slabs

The following boundaries for isoneutral slabs were defined:

  • Atlantic: -, 26, 26.5, 26.75, 27, 27.25, 27.5, 27.75, 27.85, 27.95, 28.05, 28.1, 28.15, 28.2,
  • Indo-Pacific: -, 26, 26.5, 26.75, 27, 27.25, 27.5, 27.75, 27.85, 27.95, 28.05, 28.1,

Continuous neutral densities (gamma) values from model subsetting are grouped into isoneutral slabs.

GLODAP <- m_cut_gamma(GLODAP, "gamma")
if (params_local$subsetting == "GLODAP") {

GLODAP_cruise <- GLODAP %>% 
  filter(cruise %in% params_global$cruises_meridional)

}

if (params_local$subsetting == "random") {
  
  GLODAP_cruise <- GLODAP %>% 
  filter(lon %in% params_global$lon_Atl_section)
  
}

lat_section <- 
GLODAP_cruise %>%
  ggplot(aes(lat, depth)) +
  scale_y_reverse() +
  theme(legend.position = "bottom")

lat_section +
  geom_point(aes(col = gamma_slab)) +
  scale_color_viridis_d()

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
61efb56 Donghe-Zhu 2021-01-25
c569946 Donghe-Zhu 2021-01-24
a2f0d56 Donghe-Zhu 2021-01-23
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
17dee1d jens-daniel-mueller 2021-01-13
e5cb81a Donghe-Zhu 2021-01-05
c8b76b3 jens-daniel-mueller 2020-12-19
rm(lat_section, GLODAP_cruise)
# this section was only used to calculate gamma locally, and compare it to the value provided in GLODAP data set
if (params_local$subsetting == "GLODAP") {

GLODAP_cruise <- GLODAP %>% 
  filter(cruise %in% params_global$cruises_meridional)

}

if (params_local$subsetting == "random") {
  
  GLODAP_cruise <- GLODAP %>% 
  filter(lon %in% params_global$lon_Atl_section)
  
}

library(oce)
library(gsw)
# calculate pressure from depth

GLODAP_cruise <- GLODAP_cruise %>% 
  mutate(CTDPRS = gsw_p_from_z(-depth,
                               lat))

GLODAP_cruise <- GLODAP_cruise %>% 
  mutate(THETA = swTheta(salinity = sal,
                         temperature = temp,
                         pressure = CTDPRS,
                         referencePressure = 0,
                         longitude = lon-180,
                         latitude = lat))

GLODAP_cruise <- GLODAP_cruise %>% 
  rename(LATITUDE = lat,
         LONGITUDE = lon,
         SALNTY = sal,
         gamma_provided = gamma)

library(reticulate)
source_python(
  paste(
    path_root,
    "/utilities/functions/python_scripts/",
    "Gamma_GLODAP_python.py",
    sep = ""
  )
)

GLODAP_cruise <- calculate_gamma(GLODAP_cruise)

GLODAP_cruise <- GLODAP_cruise %>% 
  mutate(gamma_delta = gamma_provided - GAMMA)

lat_section <- 
GLODAP_cruise %>%
  ggplot(aes(LATITUDE, CTDPRS)) +
  scale_y_reverse() +
  theme(legend.position = "bottom")

lat_section +
  stat_summary_2d(aes(z = gamma_delta)) +
  scale_color_viridis_c()

GLODAP_cruise %>% 
  ggplot(aes(gamma_delta))+
  geom_histogram()

rm(lat_section, GLODAP_cruise, cruises_meridional)

7 Synthetic data coverage

GLODAP <- GLODAP %>% 
  mutate(gamma_slab = factor(gamma_slab), 
         gamma_slab = factor(gamma_slab, levels = rev(levels(gamma_slab))))

for (i_basin in unique(GLODAP$basin)) {
  # i_basin <- unique(GLODAP$basin)[3]
  
  print(
    GLODAP %>%
      filter(basin == i_basin) %>%
      ggplot(aes(lat, gamma_slab)) +
      geom_bin2d(binwidth = 5) +
      scale_fill_viridis_c(
        option = "magma",
        direction = -1,
        trans = "log10"
      ) +
      scale_x_continuous(breaks = seq(-100, 100, 20),
                         limits = c(params_global$lat_min,
                                    params_global$lat_max)) +
      facet_grid(era ~ .) +
      labs(title = paste("MLR region: ", i_basin))
  )
  
}

Version Author Date
a1c8f87 Donghe-Zhu 2021-01-31
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
ceed31b Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
61efb56 Donghe-Zhu 2021-01-25
48f638e Donghe-Zhu 2021-01-25
c569946 Donghe-Zhu 2021-01-24
a2f0d56 Donghe-Zhu 2021-01-23
28509fc Donghe-Zhu 2021-01-23
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
17dee1d jens-daniel-mueller 2021-01-13
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

Version Author Date
a1c8f87 Donghe-Zhu 2021-01-31
ae5c18f Donghe-Zhu 2021-01-31
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
ceed31b Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
61efb56 Donghe-Zhu 2021-01-25
48f638e Donghe-Zhu 2021-01-25
c569946 Donghe-Zhu 2021-01-24
a2f0d56 Donghe-Zhu 2021-01-23
28509fc Donghe-Zhu 2021-01-23
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
17dee1d jens-daniel-mueller 2021-01-13
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19

7.1 Histograms

GLODAP_vars <- GLODAP %>% 
  select(params_local$MLR_target,
         params_local$MLR_predictors)

GLODAP_vars_long <- GLODAP_vars %>% 
  pivot_longer(
    cols = c(params_local$MLR_target,
             params_local$MLR_predictors),
    names_to = "variable",
    values_to = "value"
  )

GLODAP_vars_long %>% 
  ggplot(aes(value)) +
  geom_histogram() +
  facet_wrap(~ variable,
             ncol = 2,
             scales = "free")

Version Author Date
b50fe52 Donghe-Zhu 2021-01-31
ac99ae5 jens-daniel-mueller 2021-01-29
b5bdcaf Donghe-Zhu 2021-01-29
372adf5 Donghe-Zhu 2021-01-29
af8788e Donghe-Zhu 2021-01-29
21c91c9 Donghe-Zhu 2021-01-29
eded038 Donghe-Zhu 2021-01-29
541d4dd Donghe-Zhu 2021-01-29
6a75576 Donghe-Zhu 2021-01-28
16fba40 Donghe-Zhu 2021-01-28
12bc567 Donghe-Zhu 2021-01-27
342402d Donghe-Zhu 2021-01-27
5bad5c2 Donghe-Zhu 2021-01-27
48f638e Donghe-Zhu 2021-01-25
c1cec47 Donghe-Zhu 2021-01-25
05ffb0c Donghe-Zhu 2021-01-25
8b97165 Donghe-Zhu 2021-01-25
c569946 Donghe-Zhu 2021-01-24
4c28e4a Donghe-Zhu 2021-01-22
24cc264 jens-daniel-mueller 2021-01-22
7891955 Donghe-Zhu 2021-01-21
d4cf1cb Donghe-Zhu 2021-01-21
1f3e5b6 jens-daniel-mueller 2021-01-20
0e7bdf1 jens-daniel-mueller 2021-01-15
4571843 jens-daniel-mueller 2021-01-14
b3564aa jens-daniel-mueller 2021-01-14
8d032c3 jens-daniel-mueller 2021-01-14
fa85b93 jens-daniel-mueller 2021-01-06
e5cb81a Donghe-Zhu 2021-01-05
a499f10 Donghe-Zhu 2021-01-05
fb8a752 Donghe-Zhu 2020-12-23
8fae0b2 Donghe-Zhu 2020-12-21
c8b76b3 jens-daniel-mueller 2020-12-19
rm(GLODAP_vars, GLODAP_vars_long)

8 Individual cruise sections

Zonal and meridional section plots are produce for each cruise individually and are available under:

/nfs/kryo/work/jenmueller/emlr_cant/model/v_XXX/figures/Cruise_sections_histograms/

if (params_local$subsetting == "GLODAP") {
  if (params_local$plot_all_figures == "y") {
    cruises <- GLODAP %>%
      group_by(cruise) %>%
      summarise(date_mean = mean(date, na.rm = TRUE),
                n = n()) %>%
      ungroup() %>%
      arrange(date_mean)
    
    GLODAP <- full_join(GLODAP, cruises)
    
    n <- 0
    for (i_cruise in unique(cruises$cruise)) {
      # i_cruise <- unique(cruises$cruise)[1]
      # n <- n + 1
      # print(n)
      
      GLODAP_cruise <- GLODAP %>%
        filter(cruise == i_cruise) %>%
        arrange(date)
      
      cruises_cruise <- cruises %>%
        filter(cruise == i_cruise)
      
      map_plot <-
        map +
        geom_point(data = GLODAP_cruise,
                   aes(lon, lat, col = date)) +
        scale_color_viridis_c(trans = "date") +
        labs(
          title = paste(
            "Mean date:",
            cruises_cruise$date_mean,
            "| cruise:",
            cruises_cruise$cruise,
            "| n(samples):",
            cruises_cruise$n
          )
        )
      
      
      lon_section <- GLODAP_cruise %>%
        ggplot(aes(lon, depth)) +
        scale_y_reverse() +
        scale_fill_viridis_c()
      
      lon_tco2 <- lon_section +
        stat_summary_2d(aes(z = tco2))
      
      lon_talk <- lon_section +
        stat_summary_2d(aes(z = talk))
      
      lon_phosphate <- lon_section +
        stat_summary_2d(aes(z = phosphate))
      
      lon_oxygen <- lon_section +
        stat_summary_2d(aes(z = oxygen))
      
      lon_aou <- lon_section +
        stat_summary_2d(aes(z = aou))
      
      lon_phosphate_star <- lon_section +
        stat_summary_2d(aes(z = phosphate_star))
      
      lon_nitrate <- lon_section +
        stat_summary_2d(aes(z = nitrate))
      
      lon_cstar <- lon_section +
        stat_summary_2d(aes(z = cstar_tref))
      
      
      lat_section <- GLODAP_cruise %>%
        ggplot(aes(lat, depth)) +
        scale_y_reverse() +
        scale_fill_viridis_c()
      
      lat_tco2 <- lat_section +
        stat_summary_2d(aes(z = tco2))
      
      lat_talk <- lat_section +
        stat_summary_2d(aes(z = talk))
      
      lat_phosphate <- lat_section +
        stat_summary_2d(aes(z = phosphate))
      
      lat_oxygen <- lat_section +
        stat_summary_2d(aes(z = oxygen))
      
      lat_aou <- lat_section +
        stat_summary_2d(aes(z = aou))
      
      lat_phosphate_star <- lat_section +
        stat_summary_2d(aes(z = phosphate_star))
      
      lat_nitrate <- lat_section +
        stat_summary_2d(aes(z = nitrate))
      
      lat_cstar <- lat_section +
        stat_summary_2d(aes(z = cstar_tref))
      
      
      hist_tco2 <- GLODAP_cruise %>%
        ggplot(aes(tco2)) +
        geom_histogram()
      
      hist_talk <- GLODAP_cruise %>%
        ggplot(aes(talk)) +
        geom_histogram()
      
      hist_phosphate <- GLODAP_cruise %>%
        ggplot(aes(phosphate)) +
        geom_histogram()
      
      hist_oxygen <- GLODAP_cruise %>%
        ggplot(aes(oxygen)) +
        geom_histogram()
      
      hist_aou <- GLODAP_cruise %>%
        ggplot(aes(aou)) +
        geom_histogram()
      
      hist_phosphate_star <- GLODAP_cruise %>%
        ggplot(aes(phosphate_star)) +
        geom_histogram()
      
      hist_nitrate <- GLODAP_cruise %>%
        ggplot(aes(nitrate)) +
        geom_histogram()
      
      hist_cstar <- GLODAP_cruise %>%
        ggplot(aes(cstar_tref)) +
        geom_histogram()
      
      (map_plot /
          ((hist_tco2 / hist_talk / hist_phosphate / hist_cstar) |
             (
               hist_oxygen / hist_phosphate_star / hist_nitrate / hist_aou
             )
          )) |
        ((
          lat_tco2 / lat_talk / lat_phosphate / lat_oxygen / lat_aou / lat_phosphate_star / lat_nitrate / lat_cstar
        ) |
          (
            lon_tco2 / lon_talk / lon_phosphate / lon_oxygen /  lon_aou / lon_phosphate_star / lon_nitrate / lon_cstar
          )
        )
      
      ggsave(
        path = paste(
          path_version_figures,
          "Cruise_sections_histograms/",
          sep = ""
        ),
        filename = paste(
          "Cruise_date",
          cruises_cruise$date_mean,
          "count",
          cruises_cruise$n,
          "cruiseID",
          cruises_cruise$cruise,
          ".png",
          sep = "_"
        ),
        width = 20,
        height = 12
      )
      
      rm(
        map_plot,
        lon_section,
        lat_section,
        lat_tco2,
        lat_talk,
        lat_phosphate,
        lon_tco2,
        lon_talk,
        lon_phosphate,
        GLODAP_cruise,
        cruises_cruise
      )
      
    }
    
  }
  
}

9 Write files

if (params_local$subsetting == "GLODAP") {
  # select relevant columns
  GLODAP <- GLODAP %>%
    select(
      year,
      date,
      era,
      basin,
      basin_AIP,
      lat,
      lon,
      depth,
      gamma,
      gamma_slab,
      params_local$MLR_predictors,
      params_local$MLR_target
    )
  
  GLODAP %>% write_csv(paste(
    path_version_data,
    "GLODAPv2.2020_MLR_fitting_ready.csv",
    sep = ""
  ))
  
}

if (params_local$subsetting == "random") {
  # select relevant columns
  GLODAP <- GLODAP %>%
    select(
      year,
      month,
      era,
      basin,
      basin_AIP,
      lat,
      lon,
      depth,
      gamma,
      gamma_slab,
      params_local$MLR_predictors,
      params_local$MLR_target
    )
  
  GLODAP %>% write_csv(paste(
    path_version_data,
    "GLODAPv2.2020_MLR_fitting_ready.csv",
    sep = ""
  ))
}

co2_atm_tref %>%  write_csv(paste(path_version_data,
                                  "co2_atm_tref.csv",
                                  sep = ""))

sessionInfo()
R version 4.0.3 (2020-10-10)
Platform: x86_64-pc-linux-gnu (64-bit)
Running under: openSUSE Leap 15.2

Matrix products: default
BLAS:   /usr/local/R-4.0.3/lib64/R/lib/libRblas.so
LAPACK: /usr/local/R-4.0.3/lib64/R/lib/libRlapack.so

locale:
 [1] LC_CTYPE=en_US.UTF-8       LC_NUMERIC=C              
 [3] LC_TIME=en_US.UTF-8        LC_COLLATE=en_US.UTF-8    
 [5] LC_MONETARY=en_US.UTF-8    LC_MESSAGES=en_US.UTF-8   
 [7] LC_PAPER=en_US.UTF-8       LC_NAME=C                 
 [9] LC_ADDRESS=C               LC_TELEPHONE=C            
[11] LC_MEASUREMENT=en_US.UTF-8 LC_IDENTIFICATION=C       

attached base packages:
[1] stats     graphics  grDevices utils     datasets  methods   base     

other attached packages:
 [1] kableExtra_1.3.1 knitr_1.30       lubridate_1.7.9  marelac_2.1.10  
 [5] shape_1.4.5      metR_0.9.0       scico_1.2.0      patchwork_1.1.1 
 [9] collapse_1.5.0   forcats_0.5.0    stringr_1.4.0    dplyr_1.0.2     
[13] purrr_0.3.4      readr_1.4.0      tidyr_1.1.2      tibble_3.0.4    
[17] ggplot2_3.3.3    tidyverse_1.3.0  workflowr_1.6.2 

loaded via a namespace (and not attached):
 [1] fs_1.5.0                 gsw_1.0-5                webshot_0.5.2           
 [4] RColorBrewer_1.1-2       httr_1.4.2               rprojroot_2.0.2         
 [7] tools_4.0.3              backports_1.1.10         R6_2.5.0                
[10] DBI_1.1.0                colorspace_2.0-0         withr_2.3.0             
[13] tidyselect_1.1.0         compiler_4.0.3           git2r_0.27.1            
[16] cli_2.2.0                rvest_0.3.6              xml2_1.3.2              
[19] labeling_0.4.2           scales_1.1.1             checkmate_2.0.0         
[22] digest_0.6.27            rmarkdown_2.5            oce_1.2-0               
[25] pkgconfig_2.0.3          htmltools_0.5.0          dbplyr_1.4.4            
[28] highr_0.8                rlang_0.4.10             readxl_1.3.1            
[31] rstudioapi_0.13          generics_0.1.0           farver_2.0.3            
[34] jsonlite_1.7.2           magrittr_2.0.1           Matrix_1.2-18           
[37] Rcpp_1.0.5               munsell_0.5.0            fansi_0.4.1             
[40] lifecycle_0.2.0          stringi_1.5.3            whisker_0.4             
[43] yaml_2.2.1               grid_4.0.3               blob_1.2.1              
[46] parallel_4.0.3           promises_1.1.1           crayon_1.3.4            
[49] lattice_0.20-41          haven_2.3.1              hms_0.5.3               
[52] seacarb_3.2.15           pillar_1.4.7             reprex_0.3.0            
[55] glue_1.4.2               evaluate_0.14            RcppArmadillo_0.10.1.2.2
[58] data.table_1.13.6        modelr_0.1.8             vctrs_0.3.6             
[61] httpuv_1.5.4             testthat_3.0.1           cellranger_1.1.0        
[64] gtable_0.3.0             assertthat_0.2.1         xfun_0.20               
[67] broom_0.7.3              RcppEigen_0.3.3.9.1      later_1.1.0.1           
[70] viridisLite_0.3.0        ellipsis_0.3.1           here_1.0.1